Synthesis and stereochemical aspects of ethyl 1,1a,2,3,4,5,6,6a-octahydro-4-octylcyclopropa[f]indene-1-carboxylate

被引:2
|
作者
Hussain, Z
Koley, D
Hopf, H
机构
[1] Max Planck Inst Bioanorgan Chem, D-45470 Mulheim, Ruhr, Germany
[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Organ Chem, D-38106 Braunschweig, Germany
[3] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Ruhr, Germany
关键词
D O I
10.1002/hlca.200590262
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel approach for the synthesis of carbene adducts 9a/9b and 10/11 is reported. Identification of the geometric and positional isomers of carbene addition was carried out by reverscd-phase HPLC, and the establishment of the structure and configuration of 9a/9b was performed by means of 2D-NMR.
引用
收藏
页码:3263 / 3273
页数:11
相关论文
共 50 条
  • [21] Ethyl 1-benzyl-4-hydroxy-2-methyl-5-oxopyrrolidine-3-carboxylate
    Gainsford, Graeme J.
    Mason, Jennifer M.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O957 - U3364
  • [22] Ethyl 2-(4-methylbenzoyl)-2,3-dihydro-1H-indene-2-carboxylate
    Xiang, Jiachen
    Hu, Tingting
    Wang, Jungang
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O504 - +
  • [23] A SYNTHESIS OF 1-2-3-4-4A-9-10-10A-OCTAHYDRO-1-1-4A-TRIMETHYL-PHENANTHRENE
    NASIPURI, D
    CHEMISTRY & INDUSTRY, 1957, (14) : 425 - 425
  • [24] THERMOLYSIS OF 1,1',2,2',3,3',4,4', OCTAHYDRO-1,4-1',4' DIEPOXY [2.2] (1,4) NAPHTHALENOPHANE
    HALVERSON, A
    KEEHN, P
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1983, 185 (MAR): : 243 - ORGN
  • [25] An improved synthesis of ethyl 5-chloro-4-fluoro-1H-indole-2-carboxylate
    Piscitelli, Francesco
    La Regina, Giuseppe
    Silvestri, Romano
    ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 2008, 40 (02) : 204 - 208
  • [26] Ethyl 4-(4-methoxyphenyl)-2-oxo-6-phenylcyclohex-3-ene-1-carboxylate
    Fun, Hoong-Kun
    Jebas, Samuel Robinson
    Rao, Jyothi N.
    Kalluraya, B.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O2448 - U3397
  • [27] Methyl 4,4"-difluoro-5′-methoxy-1,1′:3′,1"-terphenyl-4′-carboxylate
    Fun, Hoong-Kun
    Chia, Tze Shyang
    Samshuddin, S.
    Narayana, B.
    Sarojini, B. K.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3390 - U308
  • [28] Synthesis and spectroscopic characterization and DFT study of benzyl 4-([1,1′-biphenyl]-4-yl)-2,6,6-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate
    Yildirim, Sema Ozturk
    Buyukmumcu, Zeki
    Butcher, Ray J.
    Cetin, Gokalp
    Simsek, Rahime
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1200
  • [30] Ethyl 5-amino-3-(4,6-dimethylpyrimidin-2-ylamino)-1-methyl-1H-pyrazole-4-carboxylate and ethyl 5-amino-3-(4,6-dimethylpyrimidin-2-ylamino)-1-(2-nitrophenylsulfonyl)-1H-pyrazole-4-carboxylate
    Wu, C
    Zhu, YQ
    Li, HB
    Li, JR
    Ren, XL
    Li, B
    Yang, HZ
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2005, 61 : O281 - O283