Synthesis, Crystal Structure and Properties of A Triphenyltin Schiff Complex with Salicylidene-2-aminophenol

被引：1

作者：

Zhang Fu-Xing ^{[1
]}

Wu Qian ^{[1
]}

Kuang Dai-Zhi ^{[1
]}

Yu Jiang-Xi ^{[1
]}

Jiang Wu-Jiu ^{[1
]}

Zhu Xiao-Ming ^{[1
]}

机构：

[1] Hengyang Normal Univ, Key Lab Funct Met Organ Cpds Hunan Prov, Key Lab Funct Organometall Mat, Dept Chem & Mat Sci,Coll Hunan Prov, Hengyang 421008, Hunan, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 37卷 / 02期

关键词：

triphenyltin complex with salicylidene-2-aminophenol; organotin; synthesis; crystal structure; vitro anticancer activity; BASES;

D O I：

10.14102/j.cnki.0254-5861.2011-1684

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The triphenyltin complex with salicylidene-2-aminophenol (C31H24NO2Sn, 1) has been synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, and X-ray single-crystal diffraction. The complex crystallizes in monoclinic system, P2(1)/c space group with a = 1.09515(8), b = 1.17739(8), c = 2.29075(14) nm, beta = 117.070(4)degrees, V = 2.6302(3) nm(3), Z = 4, D-c= 1.417 g/cm(3), mu = 0.999 mm(-1), F(000) = 1123, R= 0.0472 and wR= 0.1169. X-ray single-crystal diffraction showed that 1 demonstrates a one-dimensional chain structure. The quantum chemical calculation of 1 has been investigated. Complex 1 emits fluorescence at 558 nm and exhibits certain inhibitory activity against NCI-H460, A549 and MCF-7.

引用

页码：270 / 276

页数：7

共 50 条

[41] Synthesis, Crystal Structure and Magnetic Properties of Dinuclear Dy(III) Complex Based on Multidentate Schiff Base
Wang Qin
Liu Yuan-Yuan
Niu Li
Yan Jing
Hou Yin-Ling
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2022, 38 (03) : 535 - 541
[42] Synthesis, crystal structure, and fluorescence properties of a two-dimensional copper(II) complex with Schiff base
Y. H. Fan
Y. F. Wang
C. F. Bi
Q. Wang
X. Zhang
X. Y. Liu
Russian Journal of Coordination Chemistry, 2010, 36 : 509 - 513
[43] Synthesis, crystal structure, and fluorescence properties of a two-dimensional copper(II) complex with Schiff base
Fan, Y. H.
Wang, Y. F.
Bi, C. F.
Wang, Q.
Zhang, X.
Liu, X. Y.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2010, 36 (07) : 509 - 513
[44] Synthesis, crystal structure and nonlinear optical properties of nickel(II) complex with Schiff-base ligand
Xue, ZM
Zhang, XJ
Tian, YP
Wu, JY
Jiang, MH
Fun, HK
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 22 (03) : 265 - 269
[45] Synthesis, crystal structure and magnetic properties of a dinuclear manganese(III) tetradentate Schiff-base complex
Feng, Yuhua
Xu, Jinxia
Liao, Daizheng
Yan, Shiping
Jiang, Zonghui
JOURNAL OF COORDINATION CHEMISTRY, 2008, 61 (22) : 3568 - 3574
[46] Synthesis, Crystal Structure and Electrochemistry Properties of a Cobalt(II) Complex Based on Asymmetry Schiff Base Ligand
Feng Xun
Song Hong-Liang
Ye Bao-Xian
Huo Su-Zhen
Xie Shi-Yu
Guo Jin-Zhong
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33 (06) : 897 - 902
[47] Synthesis, crystal structure and photoluminescent properties of an aromatic bridged Schiff base ligand and its zinc complex
Yu, Tianzhi
Zhang, Kai
Zhao, Yuling
Yang, Changhui
Zhang, Hui
Qian, Long
Fan, Duowang
Dong, Wenkui
Chen, Lili
Qiu, Yongqing
INORGANICA CHIMICA ACTA, 2008, 361 (01) : 233 - 240
[48] Structure and properties of iron-cyclam complex of 2-aminophenol
Vasconcellos, LCG
Oliveira, CP
Castellano, EE
Ellena, J
Moreira, IS
POLYHEDRON, 2001, 20 (06) : 493 - 499
[49] Mononuclear and binuclear complexes of salicylidene Schiff bases: synthesis and mesogenic properties
Rao, Nandiraju V. S.
Choudhury, Trirup D.
Paul, Manoj K.
Francis, Tuluri
LIQUID CRYSTALS, 2009, 36 (04) : 409 - 423
[50] Synthesis and crystal structure of dipyridine-(salicylidene-1-α-aminobenzyl-2-naphthol) copper (II) complex
Zhang, Y
Zhang, L
Guo, ZJ
Zhu, LG
JOURNAL OF COORDINATION CHEMISTRY, 2002, 55 (12) : 1393 - 1396

← 1 2 3 4 5 →