Synthesis, Crystal Structure and Properties of A Triphenyltin Schiff Complex with Salicylidene-2-aminophenol

被引：1

作者：

Zhang Fu-Xing ^{[1
]}

Wu Qian ^{[1
]}

Kuang Dai-Zhi ^{[1
]}

Yu Jiang-Xi ^{[1
]}

Jiang Wu-Jiu ^{[1
]}

Zhu Xiao-Ming ^{[1
]}

机构：

[1] Hengyang Normal Univ, Key Lab Funct Met Organ Cpds Hunan Prov, Key Lab Funct Organometall Mat, Dept Chem & Mat Sci,Coll Hunan Prov, Hengyang 421008, Hunan, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 37卷 / 02期

关键词：

triphenyltin complex with salicylidene-2-aminophenol; organotin; synthesis; crystal structure; vitro anticancer activity; BASES;

D O I：

10.14102/j.cnki.0254-5861.2011-1684

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The triphenyltin complex with salicylidene-2-aminophenol (C31H24NO2Sn, 1) has been synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, and X-ray single-crystal diffraction. The complex crystallizes in monoclinic system, P2(1)/c space group with a = 1.09515(8), b = 1.17739(8), c = 2.29075(14) nm, beta = 117.070(4)degrees, V = 2.6302(3) nm(3), Z = 4, D-c= 1.417 g/cm(3), mu = 0.999 mm(-1), F(000) = 1123, R= 0.0472 and wR= 0.1169. X-ray single-crystal diffraction showed that 1 demonstrates a one-dimensional chain structure. The quantum chemical calculation of 1 has been investigated. Complex 1 emits fluorescence at 558 nm and exhibits certain inhibitory activity against NCI-H460, A549 and MCF-7.

引用

页码：270 / 276

页数：7

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