Can the glass transition be explained without a growing static length scale?

被引:41
|
作者
Berthier, Ludovic [1 ]
Biroli, Giulio [2 ,3 ]
Bouchaud, Jean-Philippe [4 ]
Tarjus, Gilles [5 ]
机构
[1] Univ Montpellier, CNRS, Lab Charles Coulomb L2C, Montpellier, France
[2] Univ Paris Saclay, CNRS, CEA, Inst Phys Theor, F-91191 Gif Sur Yvette, France
[3] Sorbonne Univ, PSL Res Univ, CNRS, Lab Phys Stat,Ecole Normale Super, F-75005 Paris, France
[4] Capital Fund Management, 23 Rue Univ, F-75007 Paris, France
[5] Sorbonne Univ, CNRS, LPTMC, UMR 7600, 4 Pl Jussieu, F-75005 Paris, France
来源
JOURNAL OF CHEMICAL PHYSICS | 2019年 / 150卷 / 09期
关键词
SUPERCOOLED LIQUIDS; METASTABLE STATES; AMORPHOUS ORDER; VISCOUS-LIQUIDS; DYNAMICS; MODELS; RELAXATION; COLLOQUIUM; ENTROPY; SYSTEMS;
D O I
10.1063/1.5086509
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It was recently discovered that SWAP, a Monte Carlo algorithm that involves the exchange of pairs of particles of differing diameters, can dramatically accelerate the equilibration of simulated supercooled liquids in regimes where the normal dynamics is glassy. This spectacular effect was subsequently interpreted as direct evidence against a static, cooperative explanation of the glass transition such as the one offered by the random first-order transition (RFOT) theory. We explain the speedup induced by SWAP within the framework of the RFOT theory. We suggest that the efficiency of SWAP stems from a postponed onset of glassy dynamics. We describe this effect in terms of "crumbling metastability" and use the example of nucleation to illustrate the possibility of circumventing free-energy barriers of thermodynamic origin by a change in the local dynamical rules. Published under license by AIP Publishing.
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页数:13
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