Can the glass transition be explained without a growing static length scale?

被引:41
|
作者
Berthier, Ludovic [1 ]
Biroli, Giulio [2 ,3 ]
Bouchaud, Jean-Philippe [4 ]
Tarjus, Gilles [5 ]
机构
[1] Univ Montpellier, CNRS, Lab Charles Coulomb L2C, Montpellier, France
[2] Univ Paris Saclay, CNRS, CEA, Inst Phys Theor, F-91191 Gif Sur Yvette, France
[3] Sorbonne Univ, PSL Res Univ, CNRS, Lab Phys Stat,Ecole Normale Super, F-75005 Paris, France
[4] Capital Fund Management, 23 Rue Univ, F-75007 Paris, France
[5] Sorbonne Univ, CNRS, LPTMC, UMR 7600, 4 Pl Jussieu, F-75005 Paris, France
来源
JOURNAL OF CHEMICAL PHYSICS | 2019年 / 150卷 / 09期
关键词
SUPERCOOLED LIQUIDS; METASTABLE STATES; AMORPHOUS ORDER; VISCOUS-LIQUIDS; DYNAMICS; MODELS; RELAXATION; COLLOQUIUM; ENTROPY; SYSTEMS;
D O I
10.1063/1.5086509
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It was recently discovered that SWAP, a Monte Carlo algorithm that involves the exchange of pairs of particles of differing diameters, can dramatically accelerate the equilibration of simulated supercooled liquids in regimes where the normal dynamics is glassy. This spectacular effect was subsequently interpreted as direct evidence against a static, cooperative explanation of the glass transition such as the one offered by the random first-order transition (RFOT) theory. We explain the speedup induced by SWAP within the framework of the RFOT theory. We suggest that the efficiency of SWAP stems from a postponed onset of glassy dynamics. We describe this effect in terms of "crumbling metastability" and use the example of nucleation to illustrate the possibility of circumventing free-energy barriers of thermodynamic origin by a change in the local dynamical rules. Published under license by AIP Publishing.
引用
收藏
页数:13
相关论文
共 50 条
  • [41] Growing length and time scales in glass-forming liquids
    Karmakar, Smarajit
    Dasguptaa, Chandan
    Sastry, Srikanth
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2009, 106 (10) : 3675 - 3679
  • [42] DSC investigation of chain cooperativity rearrangements and critical length scale of polybutadiene networks in glass transition range
    Vasile Cristian Grigoraş
    Journal of Thermal Analysis and Calorimetry, 2022, 147 : 11875 - 11882
  • [43] DSC investigation of chain cooperativity rearrangements and critical length scale of polybutadiene networks in glass transition range
    Grigoras, Vasile Cristian
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2022, 147 (21) : 11875 - 11882
  • [44] Can the Hagedorn phase transition be explained from matrix model for strings?
    Sathiapalan, B.
    Sircar, Nilanjan
    JOURNAL OF HIGH ENERGY PHYSICS, 2008, (08):
  • [45] Supergranular-scale solar convection not explained by mixing-length theory
    Hanson, Chris S.
    Das, Srijan Bharati
    Mani, Prasad
    Hanasoge, Shravan
    Sreenivasan, Katepalli R.
    NATURE ASTRONOMY, 2024, 8 (09): : 1088 - 1101
  • [46] THE GLASS-TRANSITION - DYNAMIC AND STATIC SCALING APPROACH
    SOULETIE, J
    JOURNAL DE PHYSIQUE, 1990, 51 (09): : 883 - 898
  • [47] The static lengthscale characterizing the glass transition at lower temperatures
    Gutierrez, R.
    Karmakar, S.
    Pollack, Y. G.
    Procaccia, I.
    EPL, 2015, 111 (05)
  • [48] STATIC FATIGUE TRANSITION IN OPTICAL-GLASS FIBERS
    RITTER, JE
    ROBERTS, DR
    CUELLAR, E
    KENNEDY, MT
    GLASS TECHNOLOGY, 1994, 35 (06): : 265 - 271
  • [49] On the role of the length scale in the by-pass transition
    Jonas, P
    ZEITSCHRIFT FUR ANGEWANDTE MATHEMATIK UND MECHANIK, 1997, 77 : S145 - S146
  • [50] Small characteristic length at the glass transition cooperativity onset
    Donth, E
    Kahle, S
    Korus, J
    Beiner, M
    JOURNAL DE PHYSIQUE I, 1997, 7 (04): : 581 - 598