Extended structures based on hydrogen bonding and π-π interactions:: synthesis and characterization of two zinc complexes:: [Zn(dap)Cl2] and [Zn(dap)2Cl2]

被引：10
|
作者：
de Cires-Mejias, C
Tanase, S
Reedijk, J
González-Vílchez, F
Vilaplana, R
Mills, AM
Kooijman, H
Spek, AL
机构：
[1] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands
[2] Univ Seville, Fac Chem, Dept Inorgan Chem, Bioinorgan Chem Lab, Seville 41071, Spain
[3] Univ Utrecht, Bijvoet Ctr Biomol Res, NL-3584 CH Utrecht, Netherlands
来源：
INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 05期
关键词：
zinc; aminopyridine; hydrogen bonds;
D O I：
10.1016/j.ica.2003.11.035
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new Zn(II) complexes, [Zn(dap)Cl-2] (1) and [Zn(dap)(2)Cl-2] (2) (dap stands for 2,3-diaminopyridine), were prepared and spectroscopically and crystallographically characterized. In both compounds, the zinc(II) atom has a pseudo-tetrahedral ZnN2Cl2 coordination environment. Compound I adopts a three-dimensional structure built up from [Zn(dap)Cl-2](n) zig-zag chains, which are linked by N-(HCl)-Cl-... hydrogen bonds. In compound 2 the dap is monodentate coordinating via the pyridine nitrogen the mononuclear tetrahedral [Zn(dap),Cl,] units are linked into two-dimensional sheets through extensive N-(HCl)-Cl-... hydrogen bonding. Inter-sheet pi-pi interactions connect them into a three-dimensional network. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：1494 / 1498
页数：5
相关论文
共 50 条
  • [41] COMPARISONS OF PI-BONDING AND HYDROGEN-BONDING IN ISOMORPHOUS COMPOUNDS - (CR(NH3)5CL)CL2, (CO(NH3)5CL)CL2, (RH(NH3)5CL)CL2, (IR(NH3)5CL)CL2, (RU(NH3)5CL)CL2, (OS(NH3)5CL)CL2
    HAMBLEY, TW
    LAY, PA
    INORGANIC CHEMISTRY, 1986, 25 (25) : 4553 - 4558
  • [42] Zinc selenium oxochloride, β-Zn2(SeO3)Cl2, a synthetic polymorph of the mineral sophiite
    Johnsson, Mats
    Toernroos, Karl W.
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2007, 63 : I34 - I36
  • [43] Synthesis, characterization and in vitro cytotoxicity of platinum(II) complexes of selenones [Pt(selenone)2Cl2]
    Altoum, Ali Osman S.
    Alhoshani, Ali
    Alhosaini, Khalid
    Altaf, Muhammad
    Ahmad, Saeed
    Popoola, Saheed A.
    Al-Saadi, Abdulaziz A.
    Sulaiman, Adam A.
    Isab, Anvarhusein A.
    JOURNAL OF COORDINATION CHEMISTRY, 2017, 70 (06) : 1020 - 1031
  • [44] Synthesis, structure, and thermal behavior of the complex {Co2[N(CH2CH2OH)3]2Cl2}Cl2
    Yu. A. Kondratenko
    Russian Journal of General Chemistry, 2017, 87 : 894 - 896
  • [45] Structural characterization of microemulsions in a ternary system of Zn(oct-en)2Cl2 complex/benzene/water
    Ikeda, Y
    Imae, T
    Hao, JC
    Iida, M
    Kitano, T
    Hisamatsu, N
    LANGMUIR, 2000, 16 (20) : 7618 - 7623
  • [46] Synthesis and crystal structures of the zinc amido complexes [Zn(NPh2)2]2 and [Zn(NPh2)2(THF)2]
    Putzer, MA
    Dashti-Mommertz, A
    Neumuller, B
    Dehnicke, K
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1998, 624 (02): : 263 - 266
  • [47] Synthesis, characterization, X-ray structural analysis, DFT and BSA binding study of a Zn(II) complex, [Zn(II)Cl2(nia)2].2nia
    Saini, Anju
    Sharma, Raj Pal
    Kaur, Parmjeet
    Bansal, Priti
    Krishan, Bal
    Kaur, Paramjeet
    Ferretti, Valeria
    Kandwal, Pankaj
    JOURNAL OF COORDINATION CHEMISTRY, 2021, 74 (16) : 2741 - 2763
  • [48] Synthesis, structure, and thermal behavior of the complex {Co2[N(CH2CH2OH)3]2Cl2}Cl2
    Kondratenko, Yu. A.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2017, 87 (04) : 894 - 896
  • [49] Structures and anticancer activities of a series of isomeric complexes Ru(azpy)2Cl2
    Chen, JC
    Li, J
    Wu, WJ
    Zheng, KC
    ACTA PHYSICO-CHIMICA SINICA, 2006, 22 (04) : 391 - 396
  • [50] PREPARATION, CHARACTERIZATION AND ELECTROCHEMISTRY OF BINUCLEAR COPPER（I） COMPLEXES Cu2（dppm）Cl2 AND Cu2（dppe）Cl2
    Zhen Feng XI and Dou Man JIN Henan Institute of Chemistry
    ChineseChemicalLetters, 1993, (01) : 55 - 58
12345