Extended structures based on hydrogen bonding and π-π interactions:: synthesis and characterization of two zinc complexes:: [Zn(dap)Cl2] and [Zn(dap)2Cl2]

被引：10

作者：

de Cires-Mejias, C

Tanase, S

Reedijk, J

González-Vílchez, F

Vilaplana, R

Mills, AM

Kooijman, H

Spek, AL

机构：

[1] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands

[2] Univ Seville, Fac Chem, Dept Inorgan Chem, Bioinorgan Chem Lab, Seville 41071, Spain

[3] Univ Utrecht, Bijvoet Ctr Biomol Res, NL-3584 CH Utrecht, Netherlands

来源：

INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 05期

关键词：

zinc; aminopyridine; hydrogen bonds;

D O I：

10.1016/j.ica.2003.11.035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new Zn(II) complexes, [Zn(dap)Cl-2] (1) and [Zn(dap)(2)Cl-2] (2) (dap stands for 2,3-diaminopyridine), were prepared and spectroscopically and crystallographically characterized. In both compounds, the zinc(II) atom has a pseudo-tetrahedral ZnN2Cl2 coordination environment. Compound I adopts a three-dimensional structure built up from [Zn(dap)Cl-2](n) zig-zag chains, which are linked by N-(HCl)-Cl-... hydrogen bonds. In compound 2 the dap is monodentate coordinating via the pyridine nitrogen the mononuclear tetrahedral [Zn(dap),Cl,] units are linked into two-dimensional sheets through extensive N-(HCl)-Cl-... hydrogen bonding. Inter-sheet pi-pi interactions connect them into a three-dimensional network. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：1494 / 1498

页数：5

共 50 条

[31] RHODIUM(III) COMPLEXES OF NEW N-SUBSTITUTED ALPHA-AMINE OXIME LIGANDS - SYNTHESIS AND CRYSTAL-STRUCTURES OF [RH(PHENAO)2CL2], [RH(PHETAO)2CL2], [RH(ACETANILIDOAO)2CL2] AND [RH(N-METHYL ACETANILIDOAO)2CL2]
EFE, GE
SCHLEMPER, EO
POLYHEDRON, 1992, 11 (19) : 2447 - 2458
[32] CRYSTAL AND MOLECULAR STRUCTURE OF DICHLOROBIS(ANTIPYRINE)ZINC,ZN(C11H12ON2)2CL2
CINGI, MB
NARDELLI, M
GUASTINI, C
MUSATTI, A
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1972, B 28 (MAR15): : 667 - &
[33] Supramolecular chloride bridged metal(II) dichloride diazine complexes: Crystal structures of [Cd(pyrazine)Cl-2], [Zn(pyrazine)Cl-2], and [Zn(pyrimidine)Cl-2]
Pickardt, J
Staub, B
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (07): : 947 - 951
[34] Ruthenium bipyridine complexes:: synthesis and characterisation of Ru(tmbpy)(CO)2Cl2, Ru(dmbpy)(CO)2Cl2 and [Ru(dmbpy)(CO)2Cl]2
Homanen, P
Haukka, M
Ahlgren, M
Pakkanen, TA
Baxter, PNW
Benfield, RE
Connor, JA
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 552 (1-2) : 205 - 211
[35] Ruthenium bipyridine complexes: synthesis and characterisation of Ru(tmbpy)(CO)2Cl2, Ru(dmbpy)(CO)2Cl2 and [Ru(dmbpy)(CO)2Cl]2
Homanen, P.
Haukka, M.
Ahlgren, M.
Pakkanen, T. A.
Journal of Organometallic Chemistry, 552 (01):
[36] Crystal structures and characterizations of two new selenite chlorides: 1D Ba2Zn(SeO3)2Cl2 and 2D BaZn2(SeO3)2Cl2
Li, Qiang
Geng, Lei
Lu, Hong-Yan
Dai, Kai
Cheng, Wen-Dan
JOURNAL OF SOLID STATE CHEMISTRY, 2018, 265 : 117 - 122
[37] SYNTHESIS AND MOLECULAR-STRUCTURE OF NOVEL ZINC(II) COMPLEXES - [[ZN(HL)CL2]N], [ZN2L2CL2] AND [ZN2(MU-OH)LCL2] [HL = 4-METHYL-2,6-BIS(PYRAZOL-1-YLMETHYL)PHENOL]
CHEN, CT
CHANG, WK
SHEU, SC
LEE, GH
HO, TI
LIN, YC
YU, W
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (06): : 1569 - 1573
[38] Raman and infrared spectra of bis(thiourea)zinc chloride Zn[CS(NH2)2]2Cl2 single crystal
Oussaid, M
Becker, P
Carabatos-Nedelec, C
PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1998, 207 (02): : 499 - 507
[39] Syntheses and crystal structures of two mononuclear complexes M(2-SC5H3NH-3-SiMe3)2Cl2(M = Cd, Zn)
Jin, Xiang-Lin
Tang, Ka-Luo
Jia, Shao-Juan
Tang, You-Qi
Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, 1996, 17 (07):
[40] Syntheses and Crystal Structures of Two Mononuclear Complexes M(2-SC5H3NH-3-SiMe3)2Cl2(M = Cd, Zn)
Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao, 7 (999):

← 1 2 3 4 5 →