Synthesis, crystal structure, and magnetic properties of a novel one-dimensional chain polymer based on 1-(4-nitrophenyl)-1,2,4-triazole

被引：0
|
作者：
Qian, Jin [1 ]
Wang, Jun [1 ]
Luo, Qiang [1 ]
Chen, Ning-Ning [1 ]
Tao, Jian-Qing [1 ]
机构：
[1] Yancheng Teachers Univ, Sch Chem & Environm Engn, Yancheng 224051, Jiangsu, Peoples R China
来源：
INORGANIC AND NANO-METAL CHEMISTRY | 2017年 / 47卷 / 12期
基金：
中国国家自然科学基金;
关键词：
coordination polymer; one-dimensional double chain; 1-(4-nitrophenyl)-1,2,4-triazole; benzophenone-2,4 '-dicarboxylic acid; antiferromagnetic interaction; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; LIGAND; ACID; TEMPERATURE; SERIES; COMPLEXES; 1-D;
D O I：
10.1080/24701556.2017.1357626
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A one-dimensional Co(II) complex [Co(BPDC)(NPT)](n) (1) (H2BPDC = benzophenone-2,4'-dicarboxylic acid, NPT = 1-(4-nitrophenyl)-1,2,4-triazole) has been synthesized and characterized using single crystal X-ray diffraction, IR and elemental analysis. Single-crystal X-ray diffraction analysis revealed that complex 1 is a one-dimensional double chain polymer based on [Co-2(OCO)(2)] binuclear motif. The thermal stability and magnetic properties of complex 1 have been investigated, which revealed antiferromagnetic coupling interaction exists between Co(II) ions.
引用
收藏
页码：1741 / 1745
页数：5
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