Phase Transitions in Li, K and Ag Modified Na1/2Bi1/2TiO3-SrTiO3-PbTiO3 Solid Solutions

被引:0
|
作者
Dunce, M. [1 ]
Birks, E. [1 ]
Antonova, M. [1 ]
Plaude, A. [1 ]
Sternberg, A. [1 ]
机构
[1] Univ Latvia, Inst Solid State Phys, LV-1063 Riga, Latvia
关键词
NBT; relaxors; solid solutions; phase transitions; modificators; FERROELECTRIC PROPERTIES;
D O I
10.1080/10584587.2012.730948
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Influence of moderate substitution of Na by monovalent metals Li, K and Ag on structure, phase transitions and dielectric properties of 0.4Na(1/2)Bi(1/2)TiO(3)-0.4SrTiO(3)-0.2PbTiO(3) is studied. Substitution by Li increases, while substitution by K and Ag decreases tetragonality of unit cell. Li increases, Ag decreases while K weakly influences phase transition temperature. The characteristic for the parent phase relaxor state with T-t approaching T-m in case of substitution by K and Li transfers into diffused phase transition without T-m dependence on frequency and extended region of thermal hysteresis.
引用
收藏
页码:12 / 18
页数:7
相关论文
共 50 条
  • [31] The effect of Fe-acceptor doping on the electrical properties of Na1/2Bi1/2TiO3 and 0.94 (Na1/2Bi1/2)TiO3-0.06 BaTiO3
    Steiner, Sebastian
    Seo, In-Tae
    Ren, Pengrong
    Li, Ming
    Keeble, David J.
    Froemling, Till
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2019, 102 (09) : 5295 - 5304
  • [32] Ferroelectric-ferroelectric phase coexistence in Na1/2Bi1/2TiO3
    Rao, Badari Narayana
    Fitch, Andy N.
    Ranjan, Rajeev
    PHYSICAL REVIEW B, 2013, 87 (06):
  • [33] Electrical properties of Na1/2Bi1/2TiO3-BaTiO3 ceramics
    Chu, BJ
    Chen, DR
    Li, GR
    Yin, QR
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2002, 22 (13) : 2115 - 2121
  • [34] Dynamical mechanism of phase transitions in A-site ferroelectric relaxor (Na1/2Bi1/2) TiO3
    Deng, Guochu
    Danilkin, Sergey
    Zhang, Haiwu
    Imperia, Paolo
    Li, Xiaobing
    Zhao, Xiangyong
    Luo, Haosu
    PHYSICAL REVIEW B, 2014, 90 (13):
  • [35] PYROELECTRIC PROPERTIES OF (NA1/2BI1/2)TIO3 CERAMICS
    HAGIYEV, MS
    ISMAILZADE, IH
    ABIYEV, AK
    FERROELECTRICS, 1984, 56 (3-4) : 215 - 217
  • [36] Prediction of the [Na1/2Bi1/2]TiO3 ground state
    Burton, BP
    Cockayne, E
    FUNDAMENTAL PHYSICS OF FERROELECTRICS 2001, 2001, 582 : 82 - 90
  • [37] Electronic structure of (Na1/2Bi1/2)TiO3 and its solid solution with BaTiO3
    Xu, YN
    Ching, WY
    PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 2000, 80 (06): : 1141 - 1151
  • [38] Thermal expansion, T - x phase diagram and polarization of (1-x)Na1/2Bi1/2TiO3-xBaTiO3 solid solutions
    Gorev, M. V.
    Flerov, I. N.
    Molokeev, M. S.
    Bormanis, K.
    Birks, E.
    Sapozhnikov, S. V.
    Mikhaleva, E. A.
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2024, 44 (15)
  • [39] Electronic structures and phase instabilities of cubic Na1/2Bi1/2TiO3 and K1/2Bi1/2TiO3: a first-principles comparative study
    Zhou Shu-Lan
    Zhao Xian
    Jiang Xiang-Ping
    Han Xiao-Dong
    ACTA PHYSICA SINICA, 2014, 63 (16)
  • [40] The effect of hydrogen on the fracture properties of 0.8(Na1/2Bi1/2)TiO3-0.2(K1/2Bi1/2)TiO3 ferroelectric ceramics
    Zhang, H.
    Su, Y. J.
    Qiao, L. J.
    Chu, W. Y.
    Wang, D.
    Li, Y. X.
    JOURNAL OF ELECTRONIC MATERIALS, 2008, 37 (03) : 368 - 372