Conversion of aldoximes into nitriles catalyzed by simple transition metal salt of the fourth period in acetonitrile

被引：38
|
作者：
Ma, Xiao-Yun [1 ]
He, Ying [1 ]
Lu, Ting-Ting [1 ]
Lu, Ming [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Chem Engn Coll, Nanjing 210094, Jiangsu, Peoples R China
来源：
TETRAHEDRON | 2013年 / 69卷 / 12期
基金：
中国国家自然科学基金;
关键词：
Aldoxime; Nitrile; Amide; Acetonitrile; Transition metal salt; EFFICIENT BECKMANN REARRANGEMENT; HIGHLY EFFICIENT; PRIMARY AMIDES; DEHYDRATION; MILD; ACID; TRANSFORMATION; ALDEHYDES; HYDRATION; VERSATILE;
D O I：
10.1016/j.tet.2013.01.059
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Conversion of aldoximes into nitriles catalyzed by simple transition metal catalysts, such as copper salts, nickel salts, cobalt salts, zinc salts, iron salts, and manganese salts in acetonitrile was investigated. All the metal salts display catalytic property in the conversion of aldoximes into nitriles and cupric acetate exhibits much higher activity than other catalysts. The corresponding amide was detected in almost all cases and acetonitrile was found to be involved in the conversion of aldoximes into nitriles. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2560 / 2564
页数：5
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