Transition-metal-catalyzed direct β-functionalization of simple carbonyl compounds

被引:17
|
作者
Yan, Guobing [1 ]
Borah, Arun Jyoti [1 ]
机构
[1] Lishui Univ, Dept Chem, Lishui 323000, Zhejiang, Peoples R China
来源
Organic Chemistry Frontiers | 2014年 / 1卷 / 07期
关键词
C(SP(3))-H BOND ACTIVATION; DIRECT ARYLATION; KETONES; EQUIVALENTS; PHOTOREDOX; ESTERS;
D O I
10.1039/c4qo00154k
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Chemical transformations via catalytic C-H bond activation have been established as one of the most powerful tools in organic synthetic chemistry. Transition-metal-catalyzed direct functionalization of beta-C(sp(3))-H bonds of carbonyl compounds has been developed in recent years. This highlight will focus on recent advances in this active area and their mechanisms are also discussed.
引用
收藏
页码:838 / 842
页数:5
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