Identification of calcium carbide-ripened sapota (Achras sapota) fruit by headspace SPME-GC-MS

被引：3
|
作者：
Vemula, Madhu [1 ]
Shaikh, Asif Sadiq [1 ]
Chilakala, Shireesha [1 ]
Tallapally, Maheshwari [1 ]
Upadhyayula, Vijayasarathi [1 ]
机构：
[1] CSIR Indian Inst Chem Technol, Ctr Mass Spectrometry, Acad Sci & Innovat Res, Analyt & Struct Chem Div, Hyderabad 500007, Telangana, India
来源：
FOOD ADDITIVES AND CONTAMINANTS PART A-CHEMISTRY ANALYSIS CONTROL EXPOSURE & RISK ASSESSMENT | 2020年 / 37卷 / 10期
关键词：
Post-harvest ripening; sapota fruits; sapodilla fruits; artificial ripening; calcium carbide; ethylene; solid-phase microextraction; gas chromatography - mass spectrometry;
D O I：
10.1080/19440049.2020.1794055
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The effect of post-harvest ripening by ethylene and calcium carbide was studied by headspace solid-phase microextraction gas chromatography mass spectrometry (HS-SPME-GC-MS) method. Sapota (sapodilla) fruits were ripened with ethylene gas, technical grade calcium carbide and pure calcium carbide ripeners and the samples were homogenised after complete ripening. The samples were subjected to HS-SPME-GC-MS and the obtained results showed the presence of various alcohols, aldehydes, acids, ketones and esters which were commonly present in the samples. The fruit samples ripened with technical grade calcium carbide showed the presence of 3,5-dimethyl-1,2,4-trithiolane isomers, which can be used as markers to identify sapota fruits ripened with technical grade calcium carbide. The technical grade calcium carbide contains divinyl sulphide which might have been transformed into the trithiolane isomers. These isomers were not observed in the fruits ripened with pure calcium carbide and also with ethylene gas. Hence the formation of trithiolane residues may be attributed to the presence of divinyl sulphide impurity present in calcium carbide and its conversion due to the action of ethylene releasing enzymes present in the fruits.
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页码：1601 / 1609
页数：9
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  • [1] Analysis of the Volatile Components of Pouteria sapota (Sapote Mamey) Fruit by HS-SPME-GC-MS
    Rodriguez, Candelario
    Durant-Archibold, Armando A.
    Santana, Ana
    Murillo, Enrique
    Franco Abuin, Carlos M.
    [J]. NATURAL PRODUCT COMMUNICATIONS, 2018, 13 (08) : 1027 - 1030
  • [2] Identification of odor biomarkers in irradiation injury urine based on headspace SPME-GC-MS
    Wu, Xin
    Zhu, Tong
    Zhang, Hongbing
    Lu, Lu
    He, Xin
    Liu, Changxiao
    Fan, Sai-jun
    [J]. INTERNATIONAL JOURNAL OF RADIATION BIOLOGY, 2021, 97 (11) : 1597 - 1605
  • [3] Analyzing changes in metabolite profile during postharvest ripening in Achras sapota fruits: GC-MS based metabolomics approach
    Das, S.
    De, B.
    [J]. INTERNATIONAL FOOD RESEARCH JOURNAL, 2015, 22 (06): : 2288 - 2293
  • [4] Metabolomic and chemometric study of Achras sapota L. fruit extracts for identification of metabolites contributing to the inhibition of α-amylase and α-glucosidase
    Susmita Das
    Mainak Dutta
    Koel Chaudhury
    Bratati De
    [J]. European Food Research and Technology, 2016, 242 : 733 - 743
  • [5] Metabolomic and chemometric study of Achras sapota L. fruit extracts for identification of metabolites contributing to the inhibition of α-amylase and α-glucosidase
    Das, Susmita
    Dutta, Mainak
    Chaudhury, Koel
    De, Bratati
    [J]. EUROPEAN FOOD RESEARCH AND TECHNOLOGY, 2016, 242 (05) : 733 - 743
  • [6] Thymol and carvacrol determination in a swine feed organic matrix using Headspace SPME-GC-MS
    Jonathan Lona-Ramirez, Fernando
    Lizeth Hernandez-Lopez, Nancy
    Gonzalez-Alatorre, Guillermo
    del Carmen Flores-Flores, Teresa
    Patino-Herrera, Rosalba
    Francisco Louvier-Hernandez, Jose
    [J]. REVISTA MEXICANA DE CIENCIAS PECUARIAS, 2023, 14 (01) : 78 - 93
  • [7] Discrimination of smokeless powders by headspace SPME-GC-MS and SPME-GC-ECD, and the potential implications upon training canine detection of explosives
    Harper, RJ
    Almirall, JR
    Furton, KG
    [J]. Sensors, and Command, Control, Communications, and Intelligence (C31) Technologies for Homeland Security and Homeland Defense IV, Pts 1 and 2, 2005, 5778 : 638 - 643
  • [8] Identification and quantification of flavor compounds in birch syrup using SPME-GC-MS
    Lloyd, Steven
    van den Berg, Abby
    Grimm, Casey
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [9] Optimization of the SPME-GC-MS Techniques for Analyzing Headspace Volatiles in Shrimp head of P. borealis
    Xie, Wancui
    Lian, Xin
    Yang, Xihong
    Yang, Yadong
    Mao, Danhui
    [J]. ADVANCES IN ENVIRONMENTAL TECHNOLOGIES, PTS 1-6, 2013, 726-731 : 416 - 419
  • [10] Use of headspace SPME-GC-MS for the analysis of the volatiles produced by indoor molds grown on different substrates
    Van Lancker, Fien
    Adams, An
    Delmulle, Barbara
    De Saeger, Sarah
    Moretti, Antonio
    Van Peteghem, Carlos
    De Kimpe, Norbert
    [J]. JOURNAL OF ENVIRONMENTAL MONITORING, 2008, 10 (10): : 1127 - 1133
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