Copper-catalyzed synthesis of benzocarbazoles via α-C-arylation of ketones

被引：47
|
作者：
Xie, Ruilong [1 ,2 ]
Ling, Yun [2 ]
Fu, Hua [1 ,3 ]
机构：
[1] Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Minist Educ, Beijing 100084, Peoples R China
[2] China Agr Univ, Key Lab Pesticide Chem & Applicat, Dept Appl Chem, Coll Sci,Minist Agr, Beijing 100193, Peoples R China
[3] Tsinghua Univ, Grad Sch Shenzhen, Key Lab Chem Biol Guangdong Prov, Shenzhen 518057, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 100期
基金：
中国国家自然科学基金;
关键词：
COUPLING REACTIONS; ARYL BROMIDES; PALLADIUM; EFFICIENT; DERIVATIVES; COMPLEXES; LIGANDS; ULLMANN; VERSATILE; HALIDES;
D O I：
10.1039/c2cc36403d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple and efficient copper-catalyzed method for the synthesis of 11H-benzo[a]carbazoles has been developed. The protocol uses readily available substituted 2-(2-bromophenyl)-1H-indoles and ketones as starting materials and an inexpensive catalyst system. The corresponding 11H-benzo[a] carbazoles were obtained in moderate to excellent yields.
引用
收藏
页码：12210 / 12212
页数：3
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