Copper-catalyzed synthesis of benzocarbazoles via α-C-arylation of ketones

被引：47

作者：

Xie, Ruilong ^{[1
,2
]}

Ling, Yun ^{[2
]}

Fu, Hua ^{[1
,3
]}

机构：

[1] Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Minist Educ, Beijing 100084, Peoples R China

[2] China Agr Univ, Key Lab Pesticide Chem & Applicat, Dept Appl Chem, Coll Sci,Minist Agr, Beijing 100193, Peoples R China

[3] Tsinghua Univ, Grad Sch Shenzhen, Key Lab Chem Biol Guangdong Prov, Shenzhen 518057, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 100期

基金：

中国国家自然科学基金;

关键词：

COUPLING REACTIONS; ARYL BROMIDES; PALLADIUM; EFFICIENT; DERIVATIVES; COMPLEXES; LIGANDS; ULLMANN; VERSATILE; HALIDES;

D O I：

10.1039/c2cc36403d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple and efficient copper-catalyzed method for the synthesis of 11H-benzo[a]carbazoles has been developed. The protocol uses readily available substituted 2-(2-bromophenyl)-1H-indoles and ketones as starting materials and an inexpensive catalyst system. The corresponding 11H-benzo[a] carbazoles were obtained in moderate to excellent yields.

引用

页码：12210 / 12212

页数：3

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