Solvothermal Synthesis and Crystal structure of a Two-dimensional Cd(II) Complex Based on a Flexible Carboxylate Ligand

被引：0
|
作者：
Li Dong-Ping [1 ,2 ]
Li Can-Hui
Li Jing
Chen Ping-Hua
Jiao Xiao-Yan
Li Yong-Xiu
机构：
[1] Nanchang Univ, Dept Chem, Nanchang 330031, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2012年 / 31卷 / 12期
基金：
中国国家自然科学基金;
关键词：
Cd(II) complex; solvothermal synthesis; coordination polymer;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A two-dimensional Cd(II) coordination polymer, [Cd(dtb)](n) (dtb = 5,5'-dithiobis(2-nitrobenzoic acid), has been solvothermally synthesized and characterized by elemental analysis, IR. TG analysis and single-crystal X-ray diffraction analysis. The complex crystallizes in the monoclinic P2(1)/c space group, with a = 10.7147(10), b = 7.4518(7), c = 22.053(2) angstrom, beta = 95.477(2)degrees, V = 1752.7(3) angstrom(3), Z = 4, M-r = 524.74, D-c = 1.989 g/cm(3) and F(000) = 1032. The final R = 0.0453 and wR = 0.1201 for 2950 observed reflections with I > 2 sigma(I). In the complex, the Cd(II) ion is coordinated with six oxygen atoms from four different carboxylate groups of dtb ligands and one lattice water molecule. The adjacent Cd centers are interconnected by the flexible carboxylate ligand to form a two-dimensional (2D) structure.
引用
收藏
页码：1837 / 1841
页数：5
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