Synthesis, Structure and Properties of a One-Dimensional Cd(II) Complex Based on a Chiral Ligand

被引：1
|
作者：
Chen, Y. M. [1 ]
Xiong, X. J. [1 ]
Huang, L. C. [1 ]
Chen, Y. H. [1 ]
Huang, Z. [1 ]
Zhang, W. J. [1 ]
机构：
[1] Huanggang Normal Univ, Coll Chem & Chem Engn, Hubei Key Lab Proc & Applicat Catalyt Mat, Huanggang, Peoples R China
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2020年 / 61卷 / 06期
关键词：
Cd(II) complex; chiral ligand; L-phenylalanine hydroxamic acid (L-pheHA); single crystal structure; PHOTOLUMINESCENT PROPERTIES; CRYSTAL-STRUCTURES; COORDINATION; ZN(II); ACID; NLO;
D O I：
10.1134/S0022476620060050
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 1D Cd(II) complex [Cd(L-pheA)(Ac)](n)(1)where the L-pheA(-)anion stands for the chiral ligand (L-phenylalanine hydroxamic acid) is synthesized and characterized. The single crystal X-ray analysis reveals that each Cd(II) atom is coordinated by three L-pheA(-)ligands and two acetate anions in a distorted seven-coordinated pentagonal bipyramidal configuration. By the interactions of two N-HMIDLINE HORIZONTAL ELLIPSISO and one N-HMIDLINE HORIZONTAL ELLIPSISN hydrogen bonds a 2D supramolecular network is formed. The solid-state luminescent properties of complex1are observed.
引用
收藏
页码：873 / 879
页数：7
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