Mono- and zerovalent manganese alkyl complexes supported by the α,α′-diiminato pyridine ligand:: Alkyl stabilization at the expense of catalytic performance

被引：84

作者：

Reardon, D ^{[1
]}

Aharonian, G ^{[1
]}

Gambarotta, S ^{[1
]}

Yap, GPA ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 05期

关键词：

D O I：

10.1021/om0110078

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of {[2,6-(i-Pr)(2)PhN=C(Me)](2)-(C5H3N)}MnCl2 with MeLi or Me3SiCH2Li afforded reduction toward rare examples of non-cyclopentadienyl and non-carbonyl Mn(I) and Mn(0) alkyl derivatives.

引用

页码：786 / 788

页数：3

共 22 条

[21] Metal-to-Ligand Alkyl Migration Inducing Carbon-Sulfur Bond Cleavage in Dialkyl Yttrium Complexes Supported by Thiazole-Containing Amidopyridinate Ligands: Synthesis, Characterization, and Catalytic Activity in the Intramolecular Hydroamination Reaction
Lyubov, Dmitry M.
Luconi, Lapo
Rossin, Andrea
Tuci, Giulia
Cherkasov, Anton V.
Fukin, Georgy K.
Giambastiani, Giuliano
Trifonov, Alexander A.
CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (12) : 3487 - 3499
[22] PI-CONJUGATED POLY(PYRIDINE-2,5-DIYL), POLY(2,2'-BIPYRIDINE-5,5'-DIYL), AND THEIR ALKYL DERIVATIVES - PREPARATION, LINEAR STRUCTURE, FUNCTION AS A LIGAND TO FORM THEIR TRANSITION-METAL COMPLEXES, CATALYTIC REACTIONS, N-TYPE ELECTRICALLY CONDUCTING PROPERTIES, OPTICAL-PROPERTIES, AND ALIGNMENT ON SUBSTRATES
YAMAMOTO, T
MARUYAMA, T
ZHOU, ZH
ITO, T
FUKUDA, T
YONEDA, Y
BEGUM, F
IKEDA, T
SASAKI, S
TAKEZOE, H
FUKUDA, A
KUBOTA, K
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (11) : 4832 - 4845

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