Mono- and zerovalent manganese alkyl complexes supported by the α,α′-diiminato pyridine ligand:: Alkyl stabilization at the expense of catalytic performance

被引：84
|
作者：
Reardon, D [1 ]
Aharonian, G [1 ]
Gambarotta, S [1 ]
Yap, GPA [1 ]
机构：
[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada
来源：
ORGANOMETALLICS | 2002年 / 21卷 / 05期
关键词：
D O I：
10.1021/om0110078
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of {[2,6-(i-Pr)(2)PhN=C(Me)](2)-(C5H3N)}MnCl2 with MeLi or Me3SiCH2Li afforded reduction toward rare examples of non-cyclopentadienyl and non-carbonyl Mn(I) and Mn(0) alkyl derivatives.
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收藏
页码：786 / 788
页数：3
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