Mono- and zerovalent manganese alkyl complexes supported by the α,α′-diiminato pyridine ligand:: Alkyl stabilization at the expense of catalytic performance

被引：84

作者：

Reardon, D ^{[1
]}

Aharonian, G ^{[1
]}

Gambarotta, S ^{[1
]}

Yap, GPA ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 05期

关键词：

D O I：

10.1021/om0110078

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of {[2,6-(i-Pr)(2)PhN=C(Me)](2)-(C5H3N)}MnCl2 with MeLi or Me3SiCH2Li afforded reduction toward rare examples of non-cyclopentadienyl and non-carbonyl Mn(I) and Mn(0) alkyl derivatives.

引用

页码：786 / 788

页数：3

共 22 条

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[9] Supported metallocene catalysts by surface organometallic chemistry. Synthesis, characterization, and reactivity in ethylene polymerization of oxide-supported mono- and biscyclopentadienyl zirconium alkyl complexes: Establishment of structure/reactivity relationships
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1600, American Chemical Society (123):

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