Reaction of a Stable Silylene with Tetrahydrofuran

被引：1
|
作者：
Gostevskii, B. A. [1 ]
Albanov, A. I. [1 ]
Igumenov, I. K. [2 ]
Morozova, N. B. [2 ]
Rakhlin, V. I. [1 ]
机构：
[1] Russian Acad Sci, Favorskii Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia
[2] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2008年 / 78卷 / 10期
关键词：
Silylene; Triethylsilane; Phenylmethylsilicone; Triethylphosphine; Viscous Yellowish Liquid;
D O I：
10.1134/S107036320810023X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reduction of 1,3-di-tert-butyl-2,2-dichloro-2,3-dihydro-1H-1,3,2-diazasilole with metallic potassium gave, instead of a stable silylene, 1,3-di-tert-butyl-2,3-dihydro-1H-1,3,2 lambda(2)-diazasilylolene, a product of insertion of the latter into the carbon-oxygen bond of tetrahydrofuran, 1,4-di-tert-butyl-6-oxa-1,4-diaza-5-silaspiro[4,5]dec-2-ene.
引用
收藏
页码：1952 / 1953
页数：2
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