A disilanyl dianion and a silyl dianion from a stable silylene

被引：21
|
作者：
West, R [1 ]
Schmedake, TA
Haaf, M
Becker, J
Mueller, T
机构：
[1] Univ Wisconsin, Organosilicon Res Ctr, Madison, WI 53706 USA
[2] Ben Gurion Univ Negev, Dept Chem, IL-84105 Beer Sheva, Israel
[3] Goethe Univ Frankfurt, Inst Anorgan Chem, D-60439 Frankfurt, Germany
来源：
CHEMISTRY LETTERS | 2001年 / 01期
关键词：
D O I：
10.1246/cl.2001.68
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The stable silylene, N.N'-di-t-butyl-1,3-diaza-2-sila-2-ylidene, is reduced by Na/K or C8K first to a disilanyl dianion and then to a silyl dianion. Both of these species can be derivatized by reaction with hydroxy compounds or with chlorotrimethylsilane.
引用
收藏
页码：68 / 69
页数：2
相关论文
共 50 条
  • [1] From a stable dianion to a stable carbenoid
    Cantat, Thibault
    Jacques, Xavier
    Ricard, Louis
    Le Goff, Xavier Frederic
    Mezailles, Nicolas
    Le Floch, Pascal
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (31) : 5947 - 5950
  • [2] A STABLE DIANION OF NAPHTHALENE
    SMID, J
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (03) : 655 - &
  • [3] Stable aromatic dianion in water
    Shirman, Elijah
    Ustinov, Alona
    Ben-Shitrit, Netanel
    Weissman, Haim
    Iron, Mark A.
    Cohen, Revital
    Rybtchinski, Boris
    JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (30): : 8855 - 8858
  • [4] Dianion aggregates derived from lithiation of N-silyl allylamine
    Williard, PG
    Jacobson, MA
    ORGANIC LETTERS, 2000, 2 (18) : 2753 - 2755
  • [5] PEROXIDE DIANION FINDS A STABLE HOME
    不详
    CHEMICAL & ENGINEERING NEWS, 2012, 90 (05) : 40 - 40
  • [6] THE AZULENE DIANION - A STABLE PARATROPIC SPECIES
    EDLUND, U
    ELIASSON, B
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (16) : 950 - 952
  • [7] DIBENZOPENTALENYL DIANION - A PERTURBED 12!ANNULENE DIANION
    TROST, BM
    KINSON, PL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (08) : 2591 - +
  • [8] From Borapyramidane to Borole Dianion
    Lee, Vladimir Ya.
    Sugasawa, Haruka
    Gapurenko, Olga A.
    Minyaev, Ruslan M.
    Minkin, Vladimir I.
    Gornitzka, Heinz
    Sekiguchi, Akira
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (19) : 6053 - 6056
  • [9] HIGHLY TWISTED ETHYLENE DIANION DILITHIUM STABILIZED BY PHENYL AND SILYL GROUPS
    SEKIGUCHI, A
    ICHINOHE, M
    NAKANISHI, T
    KABUTO, C
    SAKURAI, H
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1995, 68 (11) : 3215 - 3220
  • [10] From Borapyramidane to Borole Dianion
    Lee, Vladimir Ya. (leevya@chem.tsukuba.ac.jp), 2018, American Chemical Society (140)
12345