A disilanyl dianion and a silyl dianion from a stable silylene

被引：21
|
作者：
West, R [1 ]
Schmedake, TA
Haaf, M
Becker, J
Mueller, T
机构：
[1] Univ Wisconsin, Organosilicon Res Ctr, Madison, WI 53706 USA
[2] Ben Gurion Univ Negev, Dept Chem, IL-84105 Beer Sheva, Israel
[3] Goethe Univ Frankfurt, Inst Anorgan Chem, D-60439 Frankfurt, Germany
来源：
CHEMISTRY LETTERS | 2001年 / 01期
关键词：
D O I：
10.1246/cl.2001.68
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The stable silylene, N.N'-di-t-butyl-1,3-diaza-2-sila-2-ylidene, is reduced by Na/K or C8K first to a disilanyl dianion and then to a silyl dianion. Both of these species can be derivatized by reaction with hydroxy compounds or with chlorotrimethylsilane.
引用
收藏
页码：68 / 69
页数：2
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