Functionalized polynorbornenes with fragments of cholic acid and luminophore complexes of iridium(III) and copper(I) in side chains. Synthesis and photophysical properties

被引：2
|
作者：
Platonova, E. O. [1 ]
Il'icheva, A. I. [1 ]
Parshina, Yu. P. [1 ]
Rozhkov, A. V. [1 ]
Bochkarev, L. N. [1 ]
机构：
[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Ul Tropinina 49, Nizhnii Novgorod 603950, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2016年 / 86卷 / 09期
基金：
俄罗斯基础研究基金会;
关键词：
functionalized polynorbornenes; metathesis polymerization; cholic acid; iridium-containing polymers; copper-containing polymers; photophysical properties; OPENING METATHESIS POLYMERIZATION; SUBSTITUTED PYRAZOLONATE LIGANDS; ELECTROLUMINESCENT PROPERTIES; QUANTUM YIELDS; PENDANT GROUPS; COPOLYMERS; POLYMERS; DELIVERY; PHOTO;
D O I：
10.1134/S1070363216090176
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Copolymers containing fragments of cholic acid and luminophore complexes of iridium(III) and copper(I) in the side chains have been synthesized by metathesis polymerization. Photophysical properties of the obtained compounds have been investigated. Iridium-containing copolymers demonstrate intense photoluminescence of green, bluish-green and red colors. Copper-containing copolymers generate radiation of green and yellow-green colors. The color of photoluminescence of the metal-containing polymers is determined by the nature of copper(I) and iridium(III) complexes bonded to polymer chain.
引用
收藏
页码：2081 / 2087
页数：7
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