Functionalized polynorbornenes with fragments of cholic acid and luminophore complexes of iridium(III) and copper(I) in side chains. Synthesis and photophysical properties

被引：2
|
作者：
Platonova, E. O. [1 ]
Il'icheva, A. I. [1 ]
Parshina, Yu. P. [1 ]
Rozhkov, A. V. [1 ]
Bochkarev, L. N. [1 ]
机构：
[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Ul Tropinina 49, Nizhnii Novgorod 603950, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2016年 / 86卷 / 09期
基金：
俄罗斯基础研究基金会;
关键词：
functionalized polynorbornenes; metathesis polymerization; cholic acid; iridium-containing polymers; copper-containing polymers; photophysical properties; OPENING METATHESIS POLYMERIZATION; SUBSTITUTED PYRAZOLONATE LIGANDS; ELECTROLUMINESCENT PROPERTIES; QUANTUM YIELDS; PENDANT GROUPS; COPOLYMERS; POLYMERS; DELIVERY; PHOTO;
D O I：
10.1134/S1070363216090176
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Copolymers containing fragments of cholic acid and luminophore complexes of iridium(III) and copper(I) in the side chains have been synthesized by metathesis polymerization. Photophysical properties of the obtained compounds have been investigated. Iridium-containing copolymers demonstrate intense photoluminescence of green, bluish-green and red colors. Copper-containing copolymers generate radiation of green and yellow-green colors. The color of photoluminescence of the metal-containing polymers is determined by the nature of copper(I) and iridium(III) complexes bonded to polymer chain.
引用
收藏
页码：2081 / 2087
页数：7
相关论文
共 50 条
  • [21] Synthesis, photophysical and electrochemical properties of iridium(III) complexes with 2-aryl-1-phenylbenzimidazoles
    Bezzubov, S. I.
    Dolzhenko, V. D.
    Kiselev, Yu M.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 59 (06) : 571 - 577
  • [22] Iridium(III) Complexes with Sulfonyl and Fluorine Substituents: Synthesis, Stereochemistry and Effect of Functionalisation on their Photophysical Properties
    Ragni, Roberta
    Orselli, Enrico
    Kottas, Gregg S.
    Hassan Omar, Omar
    Badudri, Francesco
    Pedone, Adriana
    Naso, Francesco
    Farinola, Gianluca M.
    De Cola, Luisa
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (01) : 136 - 148
  • [23] Synthesis, photophysical and electrochemical properties of iridium(III) complexes with 2-aryl-1-phenylbenzimidazoles
    S. I. Bezzubov
    V. D. Dolzhenko
    Yu. M. Kiselev
    Russian Journal of Inorganic Chemistry, 2014, 59 : 571 - 577
  • [24] Phosphorescent Cyclometalated Iridium(III) Complexes Based on Amidate Ancillary Ligands: Their Synthesis and Photophysical Properties
    Yang, Wei
    Wang, Dawei
    Song, Qijun
    Zhang, Song
    Wang, Quan
    Ding, Yuqiang
    ORGANOMETALLICS, 2013, 32 (15) : 4130 - 4135
  • [25] Synthesis, structure, and photophysical and electrochemical properties of cyclometallated iridium(III) complexes with phenylated bipyridine ligands
    Lepeltier, M
    Lee, TKM
    Lo, KKW
    Toupet, L
    Le Bozec, H
    Guerchais, W
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (01) : 110 - 117
  • [26] Cyclometallated ionic iridium(III) binuclear complexes with a bisphenanthroline bridging ligand: Synthesis and photophysical properties
    Yu. E. Begantsova
    L. N. Bochkarev
    Russian Journal of General Chemistry, 2017, 87 : 1198 - 1203
  • [27] Cyclometallated Ionic Iridium(III) Binuclear Complexes with a Bisphenanthroline Bridging Ligand: Synthesis and Photophysical Properties
    Begantsova, Yu. E.
    Bochkarev, L. N.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2017, 87 (06) : 1198 - 1203
  • [28] Synthesis and photophysical properties of bis-cyclometallated Iridium(III)-Styryl complexes and their saturated analogues
    Lepeltier, Marc
    Lee, Terence Kwok-Ming
    Lo, Kenneth Kam-Wing
    Toupet, Loic
    Le Bozec, Hubert
    Guerchais, Veronique
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (18) : 2734 - 2747
  • [29] Neutral Mononuclear Copper(I) Complexes: Synthesis, Crystal Structures, and Photophysical Properties
    Sun, Yinghui
    Lemaur, Vincent
    Beltran, Juan I.
    Cornil, Jerome
    Huang, Jianwen
    Zhu, Juntong
    Wang, Yun
    Froehlich, Roland
    Wang, Haibo
    Jiang, Lin
    Zou, Guifu
    INORGANIC CHEMISTRY, 2016, 55 (12) : 5845 - 5852
  • [30] Intramolecular p Stacking in Cationic Iridium( III) Complexes with Phenyl- Functionalized Cyclometalated Ligands: Synthesis, Structure, Photophysical Properties, and Theoretical Studies
    Li, Peng
    Shan, Guo-Gang
    Cao, Hong-Tao
    Zhu, Dong-Xia
    Su, Zhong-Min
    Jitchati, Rukkiat
    Bryce, Martin R.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 2014 (14) : 2376 - 2382
12345