Low-temperature synthesis routes of alkali-metal molybdenum bronzes

被引：6

作者：

Eda, K ^{[1
]}

Chin, K

Whittingham, MS

机构：

[1] Kobe Univ, Fac Sci, Dept Chem, Nada Ku, Kobe, Hyogo 6578501, Japan

[2] SUNY Binghamton, Inst Mat Res, Binghamton, NY 13902 USA

来源：

CHEMISTRY LETTERS | 1999年 / 08期

关键词：

D O I：

10.1246/cl.1999.811

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We found some novel synthesis routes for alkali-metal molybdenum bronzes. The synthesis techniques are composed of simple hydrothermal treatments of mixed-valence compounds (or mixtures) with ACl or ACl+AOH aqueous solutions (A=alkali metal). Using these routes blue bronze (K0.30MoO3) and red bronze (K0.33MoO3) were obtained from hydrogen molybdenum bronze HXMoO3 or HXMoO3 + MoO3 even at 410 K.

引用

页码：811 / 812

页数：2

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