Low-temperature synthesis routes of alkali-metal molybdenum bronzes

被引：6
|
作者：
Eda, K [1 ]
Chin, K
Whittingham, MS
机构：
[1] Kobe Univ, Fac Sci, Dept Chem, Nada Ku, Kobe, Hyogo 6578501, Japan
[2] SUNY Binghamton, Inst Mat Res, Binghamton, NY 13902 USA
来源：
CHEMISTRY LETTERS | 1999年 / 08期
关键词：
D O I：
10.1246/cl.1999.811
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We found some novel synthesis routes for alkali-metal molybdenum bronzes. The synthesis techniques are composed of simple hydrothermal treatments of mixed-valence compounds (or mixtures) with ACl or ACl+AOH aqueous solutions (A=alkali metal). Using these routes blue bronze (K0.30MoO3) and red bronze (K0.33MoO3) were obtained from hydrogen molybdenum bronze HXMoO3 or HXMoO3 + MoO3 even at 410 K.
引用
收藏
页码：811 / 812
页数：2
相关论文
共 50 条
  • [31] Alkali-metal uranogermanates: Synthesis and characterization
    Chernorukov, NG
    Kortikov, VE
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2002, 47 (09) : 1283 - 1291
  • [32] SYNTHESIS OF ALKALI-METAL TRIFLUOROAQUOMANGANATES(II)
    BHATTACHARJEE, MN
    CHAUDHURI, MK
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1982, 21 (10): : 977 - 979
  • [33] SYNTHESIS AND STRUCTURE OF ALKALI-METAL TRIORGANOZINCATES
    PURDY, AP
    GEORGE, CF
    ORGANOMETALLICS, 1992, 11 (05) : 1955 - 1959
  • [34] Synthesis of alkali-metal and ammonium fluorosulfatotitanates
    Godneva, MM
    Motov, DL
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2003, 48 (05) : 652 - 657
  • [35] Lanthanum molybdenum oxide: Low-temperature synthesis and characterization
    Basu, S.
    Devi, P. Sujatha
    Maiti, H. S.
    Lee, Y.
    Hanson, J. C.
    JOURNAL OF MATERIALS RESEARCH, 2006, 21 (05) : 1133 - 1140
  • [36] MECHANOCHEMICAL ALKALI-METAL VANADATE SYNTHESIS
    MOLCHANOV, VV
    MAKSIMOV, GM
    PLYASOVA, LM
    GOIDIN, VV
    KOZHEVNIKOV, IV
    INORGANIC MATERIALS, 1993, 29 (04) : 622 - 625
  • [37] Alkali-metal uranogermanates: Synthesis and characterization
    Chernorukov, N.G.
    Kortikov, V.E.
    2002, MAIK Nauka (47):
  • [38] DIFFUSION OF ALKALI-METAL IONS IN VANADIUM OXYGEN BRONZES OF TYPE-BETA
    NOVAK, IY
    VOLKOV, VL
    FOTIEV, AA
    INORGANIC MATERIALS, 1982, 18 (01) : 77 - 80
  • [39] HIGH-TEMPERATURE SPECIFIC-HEAT OF ALKALI-METAL OXIDE VANADIUM BRONZES OF TYPE-BETA
    PLETNEVA, ED
    KHODOS, MY
    VOLKOV, VL
    FOTIEV, AA
    INORGANIC MATERIALS, 1979, 15 (05) : 670 - 672
  • [40] SOLID-STATE PROPERTIES OF SOME POLYCRYSTALLINE ALKALI-METAL TUNGSTEN BRONZES
    LAWRENCE, SA
    STEVENSON, S
    MAVADIA, K
    SERMON, PA
    PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1987, 411 (1840): : 95 - 121
12345