Low-temperature synthesis routes of alkali-metal molybdenum bronzes

被引：6
|
作者：
Eda, K [1 ]
Chin, K
Whittingham, MS
机构：
[1] Kobe Univ, Fac Sci, Dept Chem, Nada Ku, Kobe, Hyogo 6578501, Japan
[2] SUNY Binghamton, Inst Mat Res, Binghamton, NY 13902 USA
来源：
CHEMISTRY LETTERS | 1999年 / 08期
关键词：
D O I：
10.1246/cl.1999.811
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We found some novel synthesis routes for alkali-metal molybdenum bronzes. The synthesis techniques are composed of simple hydrothermal treatments of mixed-valence compounds (or mixtures) with ACl or ACl+AOH aqueous solutions (A=alkali metal). Using these routes blue bronze (K0.30MoO3) and red bronze (K0.33MoO3) were obtained from hydrogen molybdenum bronze HXMoO3 or HXMoO3 + MoO3 even at 410 K.
引用
收藏
页码：811 / 812
页数：2
相关论文
共 50 条
  • [1] LOW-TEMPERATURE SYNTHESIS OF ALKALI-METAL MOLYBDENUM BRONZES
    BANKS, E
    CARVALHO, R
    DONAHUE, E
    SRIVASTAVA, AM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 197 : 94 - INOR
  • [2] Electrocrystallization and properties of alkali-metal tungsten and molybdenum bronzes
    Drobasheva, TI
    Snezhkov, VI
    INORGANIC MATERIALS, 1998, 34 (11) : 1162 - 1165
  • [3] THE COMPOSITION AND PROPOSED STRUCTURE OF THE ALKALI-METAL LAYERED MOLYBDENUM BRONZES
    THOMAS, DM
    MCCARRON, EM
    MATERIALS RESEARCH BULLETIN, 1986, 21 (08) : 945 - 960
  • [4] CRYSTAL-GROWTH OF ALKALI-METAL MOLYBDENUM BRONZES BY A TEMPERATURE-GRADIENT FLUX TECHNIQUE
    RAMANUJACHARY, KV
    GREENBLATT, M
    MCCARROLL, WH
    JOURNAL OF CRYSTAL GROWTH, 1984, 70 (1-2) : 476 - 483
  • [5] LOW-TEMPERATURE HEAT-CAPACITY OF SOME ALKALI-METAL TUNGSTATES
    PAN, PH
    SHANKS, HR
    BEVOLO, AJ
    DANIELSON, GC
    JOURNAL OF SOLID STATE CHEMISTRY, 1980, 35 (02) : 176 - 180
  • [6] SYNTHESIS AND STRUCTURE OF NEW ALKALI-METAL MOLYBDENUM PHOSPHATES
    HAUSHALTER, R
    LII, K
    LAI, F
    RHEINGOLD, A
    SOLID STATE IONICS, 1988, 26 (02) : 158 - 158
  • [7] LOW-TEMPERATURE SPECIFIC-HEAT OF METAL-RICH ALKALI-METAL OXIDES
    GMELIN, E
    SIMON, A
    BRAMER, W
    VILLAR, R
    JOURNAL OF CHEMICAL PHYSICS, 1982, 76 (12): : 6256 - 6261
  • [8] ALKALI-METAL TUNGSTEN BRONZES AND ENHANCED TC
    LEFKOWITZ, I
    FERROELECTRICS, 1977, 16 (1-4) : 239 - 241
  • [9] CLUSTER MODEL OF ALKALI-METAL TUNGSTEN BRONZES
    CRANDALL, RS
    FAUGHNAN, BW
    PHYSICAL REVIEW B, 1977, 16 (04): : 1750 - 1752
  • [10] LOW-TEMPERATURE SYNTHESIS OF NOVEL LAYERED ALKALI METAL-MOO3 BRONZES AND HEXAGONAL BRONZES OF THE TYPE KYW1-XMOXO3
    GANGULI, AK
    GANAPATHI, L
    GOPALAKRISHNAN, J
    RAO, CNR
    JOURNAL OF SOLID STATE CHEMISTRY, 1988, 74 (01) : 228 - 231
12345