A new 3D Keggin-POM based metal-organic framework of Cu and H2biim: Assembly and properties of fluorescence and electrochemistry

被引：10
|
作者：
Shi, Zhenyu [1 ,2 ]
Peng, Jun [1 ]
Yu, Xia [1 ]
Shen, Yan [1 ]
Zhang, Zheyu [1 ]
Alimaje, Kundawlet [1 ]
Wang, Xiang [1 ]
机构：
[1] NE Normal Univ, Key Lab Polyoxometalate Sci, Minist Educ, Dept Chem, Changchun 130024, Jilin, Peoples R China
[2] Xingyi Normal Coll Nationalities, Xingyi 562400, Guizhou, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 28卷
基金：
美国国家科学基金会;
关键词：
Keggin; Metal-organic framework; Hydrothermal synthesis; Electrochemical property; CRYSTAL-STRUCTURE; ARCHITECTURES; POLYMER;
D O I：
10.1016/j.inoche.2012.10.040
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 3D Keggin-based metal-organic framework consisting of two kinds of Cu-H(2)biim chains, Cu-10(H-2-biim)(10)(PW12O40)(2)(OH)(4)center dot 5H(2)O 1 (H(2)biim=2,2'-biimidazole), has been synthesized under hydrothermal conditions. The TGA and PXRD measurements show that the framework is stable after removal of the guest water molecules. In addition, the luminescent and electrochemical properties of 1 have also been investigated. Crown Copyright (C) 2012 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：85 / 89
页数：5
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