A novel 3D (3,5)-connected metal-organic framework based on a flexible hexacarboxylate

被引:7
|
作者
Liu, Ying-Ying [1 ]
Zhang, Ting-Ting [1 ]
Ma, Jian-Fang [1 ]
Yang, Jin [1 ]
Song, Shu-Yan [2 ]
机构
[1] NE Normal Univ, Key Lab Polyoxometalate Sci, Dept Chem, Changchun 130024, Peoples R China
[2] Changchun Inst Appl Chem, State Key Lab Rare Earth Resources Utilizat, Changchun 130022, Peoples R China
基金
中国国家自然科学基金;
关键词
Cadmium; Coordination polymers; Hexacarboxylates; Luminescence; COORDINATION POLYMERS; PHOTOLUMINESCENT PROPERTIES; LIGANDS; SERIES; 2D; MOLECULES; TOPOLOGY; 1D; CYCLOHEXANEHEXACARBOXYLATE; FLUORESCENCE;
D O I
10.1016/j.inoche.2011.12.034
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel three-dimensional (3D) metal-organic framework, (Cd-2(HL)(H2O)(2)]center dot H3O center dot 0.25(imi) 1, (H6L = 5,5',5 ''-(2,4,6-trimethylbenzene-1,3,5-triyl)trismethylene-trisoxy-triisophthalic acid and imi = imidazole) has been prepared under hydrothermal condition. Compound 1 possesses a 3D (3,5)-connected framework with (5(2).8)(5.6.8)(6.8(2))(5(2).6.8(5).9.10) topology. The thermogravimetric and luminescent properties have also been studied for the compound. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:137 / 141
页数:5
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