Bis(diphenylphosphorothioyl) trisulfide

被引：1

作者：

Kulcsar, Monika ^{[1
]}

Silvestru, Anca ^{[1
]}

Vonas, Marius ^{[1
]}

机构：

[1] Univ Babes Bolyai, Fac Chem & Chem Engn, RO-400028 Cluj Napoca, Romania

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536808024070

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C24H20P2S5, the P atoms are arranged trans with respect to the S-3 group and the S = P-S-S systems have cisoid geometry, with an average S-P-S-S torsion angle of -56.7 degrees. The dihedral angles between the two phenyl rings attached to the P atoms are 87.33 (12) and 75.67 (10)degrees. In the crystal structure, the molecules are linked into chains running parallel to the a axis by weak intermolecular C H H center dot center dot center dot S hydrogen bonds. Centrosymmetrically related chains are further connected by pi-pi stacking interactions, with a centroid-to-centroid distance of 3.795 (5) angstrom.

引用

页码：O1683 / U1282

页数：12

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