Kinetics of the Solid-State Cyclization of Glycylglycine Dipeptide

被引：4

作者：

Larionov, R. A. ^{[1
]}

Akhmetshin, Sh. R. ^{[1
]}

Gerasimov, A. V. ^{[1
]}

Morozova, A. S. ^{[2
]}

Ziganshina, S. A. ^{[2
]}

Khayarov, Kh. R. ^{[1
]}

Gorbatchuk, V. V. ^{[1
]}

Ziganshin, M. A. ^{[1
]}

机构：

[1] Kazan Volga Reg Fed Univ, Butlerov Inst Chem, Kazan 420008, Russia

[2] Russian Acad Sci, Kazan Res Ctr, Zavoisky Phys Tech Inst, Kazan 420029, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 58卷 / 08期

关键词：

glycylglycine; 2; 5-diketopiperazine; solid-state cyclization; reaction kinetics; self-assembly of dipeptides; DIKETOPIPERAZINES; BACTERIA; GLYCINE; SPONGE;

D O I：

10.1134/S1070428022080024

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cyclization of glycylglycine dipeptide in the solid state under heating to form 2,5-diketopiperazine was studied, and its temperature range was determined. The possibility of using of the approaches of isoconversion kinetics to determine the kinetic parameters of the reaction, including the activation energy and the Arrhenius constant, is demonstrated. The kinetics of the solid-state cyclization of glycylglycine is best fit by the rate equation for an autocatalytic reaction. The self-assembly of glycylglycine and cyclo(glycylglycyl) from a solution in hexafluoroisopropanol on the surface of highly oriented pyrolytic graphite was studied by atomic force microscopy.

引用

页码：1076 / 1083

页数：8

共 50 条

[31] ON THE NATURE OF KINETIC NONEQUIVALENT STATES IN THE THERMAL CYCLIZATION OF POLYACIDS IN SOLID-STATE
TSAPOVETSKII, MI
LAIUS, LA
BESSONOV, MI
KOTON, MM
DOKLADY AKADEMII NAUK SSSR, 1981, 256 (04): : 912 - 915
[32] Fast Kinetics Design for Solid-State Battery Device
Wang, Yichao
Li, Xin
ADVANCED MATERIALS, 2024, 36 (15)
[33] KINETICS OF SOLID-STATE REACTION BETWEEN COPPER AND SULFUR
BASSI, PS
SHARMA, IB
INDIAN JOURNAL OF CHEMISTRY, 1974, 12 (08): : 813 - 815
[34] Basics and applications of solid-state kinetics: A pharmaceutical perspective
Khawam, A
Flanagan, DR
JOURNAL OF PHARMACEUTICAL SCIENCES, 2006, 95 (03) : 472 - 498
[35] Kinetics of a solid-state laser with polarizable saturable absorber
Mayorga-Cruz, D
Mel'nikov, IV
OPTICS EXPRESS, 2001, 9 (09): : 428 - 435
[36] THE EFFECTS OF DIMENSIONALITY AND DILUENT ON THE KINETICS OF SOLID-STATE POLYMERIZATION
FORT, T
LETTS, SA
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1982, 184 (SEP): : 59 - COLL
[37] Thermodynamics and densification kinetics in solid-state sintering of ceramics
Shi, JL
JOURNAL OF MATERIALS RESEARCH, 1999, 14 (04) : 1398 - 1408
[38] Thermodynamics and Densification Kinetics in Solid-state Sintering of Ceramics
J. L. Shi
Journal of Materials Research, 1999, 14
[39] KINETICS AND MECHANISM OF THE SOLID-STATE DECOMPOSITION OF PROPANTHELINE BROMIDE
YOSHIOKA, S
UCHIYAMA, M
JOURNAL OF PHARMACEUTICAL SCIENCES, 1986, 75 (01) : 92 - 96
[40] DISSOLUTION KINETICS OF SOLID-STATE IN UNSTEADY VOLUME LIQUID
PRIBYTKOV, GA
ZHURNAL FIZICHESKOI KHIMII, 1977, 51 (01): : 211 - 213

← 1 2 3 4 5 →