Borrowing hydrogen activity of NH2-MIL-125 for N-alkylation of amines with alcohols under solvent and base free condition

被引：11
|
作者：
Patel, Nisha B. [1 ]
Vala, Naresh [2 ]
Shukla, Atindra [2 ]
Neogi, Subhadip [3 ]
Mishra, Manish Kumar [1 ]
机构：
[1] Sardar Patel Univ, Dept Chem, Vallabh Vidyanagar 388120, Gujarat, India
[2] Dharmsinh Desai Univ, Shah Schulman Ctr Surface Sci & Nanotechnol, Coll Rd, Nadiad 387001, Gujarat, India
[3] CSIR, Dept Inorgan Mat & Catalysis, Cent Salt & Marine Chem Res Inst CSMCRI, GB Marg, Bhavnagar 364002, Gujarat, India
来源：
CATALYSIS COMMUNICATIONS | 2020年 / 144卷
关键词：
Borrowing hydrogen methodology; metal-organic frameworks; NH2-MIL-125; N-alkylation of amines; alcohols; ONE-POT; CATALYSTS; KETONES;
D O I：
10.1016/j.catcom.2020.106085
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The NH2-MIL-125 showed excellent activity in solvent and base free N-alkylation of amines with alcohols via borrowing hydrogen mechanism. The Ti-O clusters of NH2-MIL-125 provide acidic-basic active sites for the catalysis of reaction. The NH2-MIL-125 was found to be stable and reusable in the reaction.
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页数：5
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