Borrowing hydrogen activity of NH2-MIL-125 for N-alkylation of amines with alcohols under solvent and base free condition

被引：11
|
作者：
Patel, Nisha B. [1 ]
Vala, Naresh [2 ]
Shukla, Atindra [2 ]
Neogi, Subhadip [3 ]
Mishra, Manish Kumar [1 ]
机构：
[1] Sardar Patel Univ, Dept Chem, Vallabh Vidyanagar 388120, Gujarat, India
[2] Dharmsinh Desai Univ, Shah Schulman Ctr Surface Sci & Nanotechnol, Coll Rd, Nadiad 387001, Gujarat, India
[3] CSIR, Dept Inorgan Mat & Catalysis, Cent Salt & Marine Chem Res Inst CSMCRI, GB Marg, Bhavnagar 364002, Gujarat, India
来源：
CATALYSIS COMMUNICATIONS | 2020年 / 144卷
关键词：
Borrowing hydrogen methodology; metal-organic frameworks; NH2-MIL-125; N-alkylation of amines; alcohols; ONE-POT; CATALYSTS; KETONES;
D O I：
10.1016/j.catcom.2020.106085
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The NH2-MIL-125 showed excellent activity in solvent and base free N-alkylation of amines with alcohols via borrowing hydrogen mechanism. The Ti-O clusters of NH2-MIL-125 provide acidic-basic active sites for the catalysis of reaction. The NH2-MIL-125 was found to be stable and reusable in the reaction.
引用
收藏
页数：5
相关论文
共 48 条
  • [21] Aromatic heterocycle-grafted NH2-MIL-125(Ti) via conjugated linker with enhanced photocatalytic activity for selective oxidation of alcohols under visible light
    Wu, Zhenyu
    Huang, Xiubing
    Zheng, Haiyan
    Wang, Peng
    Hai, Guangtong
    Dong, Wenjun
    Wang, Ge
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 224 : 479 - 487
  • [22] Catalytic activity of Cu-BTC metal organic framework for borrowing hydrogen and tandem reactions of an alcohol under solvent and base free condition
    Patel, Nisha B.
    Vala, Naresh
    Shukla, Atindra
    Neogi, Subhadip
    Mishra, Manish Kumar
    INORGANICA CHIMICA ACTA, 2023, 554
  • [23] Room temperature N-alkylation of amines with alcohols under UV irradiation catalyzed by Cu-Mo/TiO2
    Zhang, Lina
    Zhang, Yan
    Deng, Youquan
    Shi, Feng
    CATALYSIS SCIENCE & TECHNOLOGY, 2015, 5 (06) : 3226 - 3234
  • [24] Activity enhancement of Ru/CeO2 for N-alkylation of amines with alcohols through tailoring metal-support interaction
    Zou, Yiwen
    Dong, Lin
    Yan, Siyang
    Liu, Jiaxu
    Mu, Lili
    Li, Licheng
    Hu, Yue
    Qi, Haifeng
    Mao, Shanjun
    Chen, Zupeng
    JOURNAL OF CATALYSIS, 2024, 429
  • [25] First used of Alkylbenzimidazole-Cobalt(II) complexes as a catalyst for the N -Alkylation of amines with alcohols under solvent -free medium
    Sahin, Neslihan
    Yildirim, Ilkay
    Ozdemir, Namik
    Gurbuz, Nevin
    Ozdemir, Ismail
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2020, 918
  • [26] A Fe single atom on N,S-doped carbon catalyst for performing N-alkylation of aromatic amines under solvent-free conditions
    Lu, Guo-Ping
    Shan, Hongbin
    Lin, Yamei
    Zhang, Kai
    Zhou, Baojing
    Zhong, Qin
    Wang, Pengcheng
    JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (44) : 25128 - 25135
  • [27] Coupling MOF-based photocatalysis with Pd catalysis over Pd@MIL-100 (Fe) for efficient N-alkylation of amines with alcohols under visible light
    Wang, Dengke
    Li, Zhaohui
    JOURNAL OF CATALYSIS, 2016, 342 : 151 - 157
  • [28] Ruthenium(II)-NHC-catalyzed (NHC = perhydrobenzimidazol-2-ylidene) alkylation of amines using the hydrogen borrowing methodology under solvent-free conditions
    Yigit, Murat
    Karaca, Emine Ozge
    Yigit, Beyhan
    Gurbuz, Nevin
    Ozdemir, Ismail
    TRANSITION METAL CHEMISTRY, 2019, 44 (06) : 565 - 573
  • [29] Ruthenium(II)-NHC-catalyzed (NHC = perhydrobenzimidazol-2-ylidene) alkylation of amines using the hydrogen borrowing methodology under solvent-free conditions
    Murat Yiğit
    Emine Özge Karaca
    Beyhan Yiğit
    Nevin Gürbüz
    İsmail Özdemir
    Transition Metal Chemistry, 2019, 44 : 565 - 573
  • [30] Degradation of diclofenac in water under LED irradiation using combined g-C3N4/NH2-MIL-125 photocatalysts
    Muelas-Ramos, V.
    Sampaio, M. J.
    Silva, C. G.
    Bedia, J.
    Rodriguez, J. J.
    Faria, J. L.
    Belver, C.
    JOURNAL OF HAZARDOUS MATERIALS, 2021, 416
12345