Borrowing hydrogen activity of NH2-MIL-125 for N-alkylation of amines with alcohols under solvent and base free condition

被引：11
|
作者：
Patel, Nisha B. [1 ]
Vala, Naresh [2 ]
Shukla, Atindra [2 ]
Neogi, Subhadip [3 ]
Mishra, Manish Kumar [1 ]
机构：
[1] Sardar Patel Univ, Dept Chem, Vallabh Vidyanagar 388120, Gujarat, India
[2] Dharmsinh Desai Univ, Shah Schulman Ctr Surface Sci & Nanotechnol, Coll Rd, Nadiad 387001, Gujarat, India
[3] CSIR, Dept Inorgan Mat & Catalysis, Cent Salt & Marine Chem Res Inst CSMCRI, GB Marg, Bhavnagar 364002, Gujarat, India
来源：
CATALYSIS COMMUNICATIONS | 2020年 / 144卷
关键词：
Borrowing hydrogen methodology; metal-organic frameworks; NH2-MIL-125; N-alkylation of amines; alcohols; ONE-POT; CATALYSTS; KETONES;
D O I：
10.1016/j.catcom.2020.106085
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The NH2-MIL-125 showed excellent activity in solvent and base free N-alkylation of amines with alcohols via borrowing hydrogen mechanism. The Ti-O clusters of NH2-MIL-125 provide acidic-basic active sites for the catalysis of reaction. The NH2-MIL-125 was found to be stable and reusable in the reaction.
引用
收藏
页数：5
相关论文
共 48 条
  • [1] N-coordinated Ru(II) catalyzed solvent free N-alkylation of primary amines with alcohols through borrowing hydrogen strategy
    Patel, Bhavya
    Ranjan, Rishi
    Chauhan, Nimesh R.
    Mukhopadhyay, Suman
    Choudhury, Angshuman Roy
    Vyas, Komal M.
    NEW JOURNAL OF CHEMISTRY, 2023, 47 (17) : 8305 - 8317
  • [2] Ruthenium-Catalyzed N-Alkylation of Amines with Alcohols under Mild Conditions Using the Borrowing Hydrogen Methodology
    Enyong, Arrey B.
    Moasser, Bahram
    JOURNAL OF ORGANIC CHEMISTRY, 2014, 79 (16): : 7553 - 7563
  • [3] Solid base catalyzed highly efficient N-alkylation of amines with alcohols in a solvent-free system
    Lu, X. -H.
    Sun, Y. -W.
    Wei, X. -L
    Peng, C.
    Zhou, D.
    Xia, Q. -H.
    CATALYSIS COMMUNICATIONS, 2014, 55 : 78 - 82
  • [4] Titanium-Catalyzed Selective N-Alkylation of Amines with Alcohols via Borrowing Hydrogen Methodology
    Upadhyay, Rahul
    Maurya, Sushil K.
    JOURNAL OF ORGANIC CHEMISTRY, 2023, 88 (24): : 16960 - 16966
  • [5] Iron-Catalyzed N-Alkylation of Secondary Amines with Alcohols Using Borrowing Hydrogen Strategy
    Qu, Ruxin
    Cheng, Yaxuan
    Yang, Siwei
    Zhao, Chaoyu
    Liu, Huiling
    Huang, Xuri
    CHEMISTRYSELECT, 2021, 6 (17): : 4089 - 4097
  • [6] Ru(II)-NHC catalysed N-Alkylation of amines with alcohols under solvent-free conditions
    Karaca, Emine Ozge
    Dehimat, Zieneb Imene
    Yasar, Sedat
    Gurbuz, Nevin
    Tebbani, Dahmane
    Cetinkaya, Bekir
    Ozdemir, Ismail
    INORGANICA CHIMICA ACTA, 2021, 520
  • [7] Discovering the role of N-heterocyclic carbene as hydrogen borrowing organocatalyst: metal-free, direct N-alkylation of amines with benzyl alcohols
    Sharma, Richa
    Rahaman, T. A. Abdul
    Sen, Janmejaya
    Mashevskaya, Irina V. V.
    Chaudhary, Sandeep
    ORGANIC CHEMISTRY FRONTIERS, 2023, 10 (03): : 730 - 744
  • [8] Cyclometalated Iridium Complex-Catalyzed N-Alkylation of Amines with Alcohols via Borrowing Hydrogen in Aqueous Media
    Luo, NianHua
    Zhong, YuHong
    Wen, HuiLing
    Luo, Renshi
    ACS OMEGA, 2020, 5 (42): : 27723 - 27732
  • [9] N-alkylation of amines with alcohols over alumina-entrapped Ag catalysts using the "borrowing hydrogen" methodology
    Liu, Huihui
    Chuah, Gaik-Khuan
    Jaenicke, Stephan
    JOURNAL OF CATALYSIS, 2012, 292 : 130 - 137
  • [10] Transition-Metal-Free Hydrogen Autotransfer: Diastereoselective N-Alkylation of Amines with Racemic Alcohols
    Xiao, Miao
    Yue, Xin
    Xu, Ruirui
    Tang, Weijun
    Xue, Dong
    Li, Chaoqun
    Lei, Ming
    Xiao, Jianliang
    Wang, Chao
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (31) : 10528 - 10536
12345