Iron-Catalyzed Intramolecular Reductive Coupling of Unactivated Aldehydes and Arylalkenes with Isopropanol

被引：5
|
作者：
Zheng, Yan-Long [1 ,2 ]
Liu, Yan-Yao [1 ,2 ]
Xu, Xue-Tao [3 ]
Zhang, Kun [3 ]
Ye, Mengchun [1 ,2 ,3 ]
机构：
[1] Nankai Univ, State Key Lab, Coll Chem, Tianjin 300071, Peoples R China
[2] Nankai Univ, Inst Elementoorgan Chem, Coll Chem, Tianjin 300071, Peoples R China
[3] Wuyi Univ, Sch Chem & Environm Engn, Jiangmen 529020, Peoples R China
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 7卷 / 03期
基金：
中国国家自然科学基金;
关键词：
alcohol; aldehyde; alkene; iron catalysis; reductive coupling; TRANSFER HYDROGENATIVE COUPLINGS; OXIDATIVE CYCLIZATION; ALDOL CYCLIZATIONS; KETONES; ETA(2)-ALKENE; 1,3-DIENE; COMPLEX; ENONES;
D O I：
10.1002/ajoc.201700622
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
FeCl3-catalyzed intramolecular reductive coupling of unactivated aldehydes and arylalkenes with isopropanol as a terminal reductant under mild and easy-to-handle conditions has been developed. A series of five-, six-, seven- and eight-membered carbocyclic alcohols were synthesized in moderate to excellent yields with high regioselectivities.
引用
收藏
页码：554 / 557
页数：4
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