Magnetic order in the organic-inorganic layer compound (CD3PO3)Mn•D2O:: a neutron and synchrotron X-ray powder diffraction study

被引：7
|
作者：
Carling, Simon G.
Visser, Dirk
Day, Peter
机构：
[1] UCL Royal Inst Great Britain, Davy Faraday Res Lab, London W1S 4BS, England
[2] Rutherford Appleton Lab, ISIS Facil, NWO Phys, Didcot OX11 0QX, Oxon, England
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2006年 / 16卷 / 26期
关键词：
D O I：
10.1039/b602874h
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Both long- and short-range magnetic order in the organic - inorganic layer compound (CD3PO3) Mn center dot D2O has been studied by temperature- dependent powder neutron diffraction. Above 15 K the magnetic intensity is dominated by diffuse scattering due to two-dimensional short-range order while at lower temperatures Bragg diffraction indicates three-dimensional order. The long- range ordered magnetic structure is similar to that of AMnPO(4) center dot D2O ( A = K, ND4). The crystal structure of (CD3PO3) Mn center dot D2O has been refined from neutron and synchrotron X-ray powder diffraction, including location of all D atoms.
引用
收藏
页码：2698 / 2701
页数：4
相关论文
共 50 条
  • [21] X-Ray Diffraction Study of New Organic Compound n-Tol3Sb[OC(O)CH=CHPh]2
    A. L. Murgin
    T. I. Ovsetsina
    A. I. Maleeva
    P. V. Andreev
    N. V. Somov
    A. V. Gushchin
    Crystallography Reports, 2020, 65 : 449 - 452
  • [22] X-Ray Diffraction Study of New Organic Compound n-Tol3Sb[OC(O)CH=CHPh]2
    Murgin, A. L.
    Ovsetsina, T., I
    Maleeva, A., I
    Andreev, P., V
    Somov, N., V
    Gushchin, A., V
    CRYSTALLOGRAPHY REPORTS, 2020, 65 (03) : 449 - 452
  • [23] Cation ordering in cubic and monoclinic (Y,Eu)(2)O-3: An x-ray powder diffraction and magnetic susceptibility study
    Antic, B
    Mitric, M
    Rodic, D
    JOURNAL OF PHYSICS-CONDENSED MATTER, 1997, 9 (02) : 365 - 374
  • [24] A neutron, X-ray and electron diffraction study of the structures of Pb3O2X2 (X = Cl, Br)
    Norén, L
    Tan, ESQ
    Withers, RL
    Sterns, M
    Rundlöf, H
    MATERIALS RESEARCH BULLETIN, 2002, 37 (08) : 1431 - 1442
  • [25] THE ABINITIO CRYSTAL-STRUCTURE DETERMINATION OF CUPT3O6 FROM A COMBINATION OF SYNCHROTRON X-RAY AND NEUTRON POWDER DIFFRACTION DATA
    HRILJAC, JA
    PARISE, JB
    KWEI, GH
    SCHWARTZ, KB
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1991, 52 (10) : 1273 - 1279
  • [26] Cation ordering/disordering kinetics in Ba3CoNb2O9:: An in situ study using synchrotron x-ray powder diffraction
    Mallinson, P. M.
    Claridge, J. B.
    Rosseinsky, M. J.
    Ibberson, R. M.
    Wright, J. P.
    Fitch, A. N.
    Price, T.
    Iddles, D. M.
    APPLIED PHYSICS LETTERS, 2007, 91 (22)
  • [27] Optical, synchrotron X-ray and neutron diffraction investigations of structural changes in the layered compound K2Na[Ag(CN)2]3
    Larochelle, CL
    Omary, MA
    Patterson, HH
    Fischer, P
    Fauth, F
    Allenspach, P
    Lucas, B
    Pattison, P
    SOLID STATE COMMUNICATIONS, 2000, 114 (03) : 155 - 160
  • [28] Coherent 3D nanostructure of γ-Al2O3: Simulation of whole X-ray powder diffraction pattern
    Pakharukova, V. P.
    Yatsenko, D. A.
    Gerasimov, E. Yu.
    Shalygin, A. S.
    Martyanov, O. N.
    Tsybulya, S. V.
    JOURNAL OF SOLID STATE CHEMISTRY, 2017, 246 : 284 - 292
  • [29] Combined powder neutron and X-ray diffraction study of charge and orbital order in Bi0.75Sr0.25MnO3
    Goff, R. J.
    Attfield, J. P.
    JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (05) : 1369 - 1374
  • [30] Valence contrast between iron sites in α-Fe2PO5. A comparative study by magnetic neutron and resonant X-ray powder diffraction
    Warner, Joanne K.
    Cheetham, Anthony K.
    Cox, David E.
    Von Dreele, Robert B.
    Journal of the American Chemical Society, 1992, 114 (15):
12345