The synthesis, structure and third-order nonlinear optical effect of a new 2D cluster polymer based on a [WS4Cu4]2+ SBU and 1,2-di(pyridin-4-yl)ethane

被引：14

作者：

Zhang, Ming-Dao ^{[1
]}

Qin, Ling ^{[1
]}

Yao, Xiao-Qiang ^{[1
]}

Yang, Qing-Xiang ^{[1
]}

Guo, Zi-Jian ^{[1
]}

Zheng, He-Gen ^{[1
]}

机构：

[1] Nanjing Univ, Nanjing Natl Lab Microstruct, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

来源：

CRYSTENGCOMM | 2013年 / 15卷 / 36期

关键词：

METAL-ORGANIC FRAMEWORK; CRYSTAL; UNITS; ARRAYS;

D O I：

10.1039/c3ce41033a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The self-assembly reaction of a multinodal preformed cluster with 1,2-di(pyridin-4-yl)ethane as the organic ligand afforded the 2D cluster polymer (1), {[(WS4Cu4)I-2(dpe)(2)](DMF)(4)}(n). There is a cavity between each two nearby dpe ligands in 1. The [WS4Cu4](2+) units are fixed by I- ions, which is attributed to the multinodal feature of the W-S-Cu secondary building units, and therefore, the cavities in 1 are settled. The NLO properties show that 1 exhibits an optical self-focusing behavior and reverse saturable absorption effects. This work provides us with useful clues to further explore the 2D W-Cu-S-based cluster polymer with cavities.

引用

页码：7354 / 7359

页数：6

共 50 条

[41] Crystal structure of a novel cadmium sulfate coordination polymer based on the multidentate 2-(3-(4-(pyridin-4-yl)phenyl)-1H-1,2,4-triazol-5-yl) pyridine ligand
F. -L. Liu
X. -P. Wang
D. Sun
Journal of Structural Chemistry, 2014, 55 : 932 - 936
[42] Crystal structure of a novel cadmium sulfate coordination polymer based on the multidentate 2-(3-(4-(pyridin-4-yl)phenyl)-1H-1,2,4-triazol-5-yl) pyridine ligand
Liu, F. -L.
Wang, X. -P.
Sun, D.
JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 55 (05) : 932 - 936
[43] Synthesis, structure, growth, optical, and thermal studies of a third-order nonlinear optical single crystal: 4-dimethylaminobenzaldehyde 2,4-dinitrophenol (DMBDN)
Santha, A.
Girisun, T. C. Sabari
Ganesamoorthy, S.
Brahadeeswaran, S.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2024, 35 (18)
[44] Synthesis and Crystal Structure of 2D Coordination Polymer {[Cu(dps)2(DMSO)2](ClO4)2}n Based on 4,4-Dipyridyl Sulfide
Morozov, A. N.
Popov, L. D.
Tkachev, V. V.
Raspopova, E. A.
Chetverikova, V. A.
Lyubchenko, S. N.
Shilov, G. V.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2019, 89 (01) : 82 - 86
[45] Synthesis, crystal structure and third-order nonlinear optical properties of heterometallic cluster [WM2S4(Pph3)3]•DMF (M2=1.25Ag+0.75Cu)
Zhang, Zhao-Xia
Li, Yong
Li, Ke-Chang
Song, Wen-Dong
Li, Qiu-Shun
Xiong, Hao-Ping
Xu, Ji-Qing
Pan, Ling-Yun
JOURNAL OF MOLECULAR STRUCTURE, 2006, 791 (1-3) : 117 - 121
[46] Crystal structure of 2,3-dihydro-2,2-di(pyridin-2-yl)-1H-benzo[d]-imidazole, C17H14N4
Habarurema, Gratien
Gerber, Thomas I. A.
Hosten, Eric C.
Betz, Richard
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2015, 230 (02): : 171 - 173
[47] Synthesis, Crystal Structure, and Properties of the Novel 2D Cd Coordination Polymer Based on Cd4 Cluster Chains
Ling-Yan Zhao
Lei Feng
Xiao-Chen Deng
Li-Wei Liu
Li Ren
Journal of Cluster Science, 2018, 29 : 1023 - 1029
[48] Synthesis, Crystal Structure, and Properties of the Novel 2D Cd Coordination Polymer Based on Cd4 Cluster Chains
Zhao, Ling-Yan
Feng, Lei
Deng, Xiao-Chen
Liu, Li-Wei
Ren, Li
JOURNAL OF CLUSTER SCIENCE, 2018, 29 (06) : 1023 - 1029
[49] Synthesis, crystal structure and third-order nonlinear optical properties of a novel coordination polymer [Cd(en)(NO3)2(4,4′-bpy)]n containing three kinds of ligands (en = ethylenediamine)
Li, L
Chen, BY
Song, YL
Li, G
Hou, HW
Fan, YT
Mi, LW
INORGANICA CHIMICA ACTA, 2003, 344 : 95 - 101
[50] Synthesis and structure of the new hybrid coordination polymer [Cu2(OAc)4(1,2-bis(4-pyridyl)ethane)]•2H2O:: Exhibiting an unusual binuclear metal environment.
Gerth, KA
Smith, MD
zur Loye, HC
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : U312 - U312

← 1 2 3 4 5 →