The synthesis, structure and third-order nonlinear optical effect of a new 2D cluster polymer based on a [WS4Cu4]2+ SBU and 1,2-di(pyridin-4-yl)ethane

被引：14
|
作者：
Zhang, Ming-Dao [1 ]
Qin, Ling [1 ]
Yao, Xiao-Qiang [1 ]
Yang, Qing-Xiang [1 ]
Guo, Zi-Jian [1 ]
Zheng, He-Gen [1 ]
机构：
[1] Nanjing Univ, Nanjing Natl Lab Microstruct, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
CRYSTENGCOMM | 2013年 / 15卷 / 36期
关键词：
METAL-ORGANIC FRAMEWORK; CRYSTAL; UNITS; ARRAYS;
D O I：
10.1039/c3ce41033a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The self-assembly reaction of a multinodal preformed cluster with 1,2-di(pyridin-4-yl)ethane as the organic ligand afforded the 2D cluster polymer (1), {[(WS4Cu4)I-2(dpe)(2)](DMF)(4)}(n). There is a cavity between each two nearby dpe ligands in 1. The [WS4Cu4](2+) units are fixed by I- ions, which is attributed to the multinodal feature of the W-S-Cu secondary building units, and therefore, the cavities in 1 are settled. The NLO properties show that 1 exhibits an optical self-focusing behavior and reverse saturable absorption effects. This work provides us with useful clues to further explore the 2D W-Cu-S-based cluster polymer with cavities.
引用
收藏
页码：7354 / 7359
页数：6
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