The hydrothermal synthesis and structure of a one-dimensional Fe(II)molybdophosphate

被引：41
|
作者：
Zhou, YS [1 ]
Zhang, LJ
You, XZ
Natarajan, S
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Coordinat Chem Inst, Nanjing 210093, Peoples R China
[2] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 12期
关键词：
hydrothermal synthesis; one-dimensional structure; Fe(II); phosphate; molecular structure;
D O I：
10.1016/S1387-7003(01)00310-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new one-dimensional Fe(II)molybdophosphate of the formula, [(C10H8N2)H-2](2)[(Fe4Mo12(V))-Mo-(II)(HPO4)(6)(PO4)(2)(H2O)(8)(OH)(6)O-24]. 8H(2)O, (1), has been synthesized by employing hydrothermal methods and characterized by single crystal X-ray diffraction. The structure consists of a network Of MO6 (M = Fe, Mo) octahedra and (H)PO4 tetrahedra linked through their vertices. The connectivity between the polyhedral units gives rise to one-dimensional chains with eight-membered apertures. The hydrogen bonded interactions between the chains form pseudo two-dimensional layers. Extensive hydrogen bonding also exists between the amine molecule, 4,4'-bipyridine, water molecule and framework oxygen atoms. Crystal data for 1: monoclinic, space group = P2(1) (no. 4), a = 12.549(3) (Angstrom), b = 23.496(5) (Angstrom), c = 14.551(3) (Angstrom), beta = 114.87(3)degrees, V = 3892.5(15) Angstrom (3), and Z = 2. (C) 2001 Published by Elsevier Science B.V.
引用
收藏
页码：699 / 704
页数：6
相关论文
共 50 条
  • [31] Hydrothermal synthesis and crystal structure of a Cadmium(II) polymer with one-dimensional chain structure:: [Cd(MDPPz)(BDQ(H2O)]n
    Li Chuan-Bi
    Zhou Shi
    Li Xiu-Mei
    Liu Bo
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26 (11) : 1349 - 1352
  • [32] Structure-property studies of a new one-dimensional Fe(III)/Mn(II) chain
    Zhang, Yuan-Zhu
    Rath, Nigam P.
    Cain, John M.
    Meisel, Mark W.
    Holmes, Stephen M.
    POLYHEDRON, 2020, 179
  • [33] Hydrothermal synthesis of one-dimensional ZnO/CdS core/shell nanocomposites
    Luo, Yonglan
    COLLOID JOURNAL, 2009, 71 (03) : 370 - 374
  • [34] Hydrothermal synthesis of one-dimensional ZnO/CdS core/shell nanocomposites
    Yonglan Luo
    Colloid Journal, 2009, 71 : 370 - 374
  • [35] Hydrothermal synthesis of one-dimensional ZnO nanostructures with different aspect ratios
    Cheng, B
    Samulski, ET
    CHEMICAL COMMUNICATIONS, 2004, (08) : 986 - 987
  • [36] Synthesis, Structure and Properties of a One-Dimensional Cd(II) Complex Based on a Chiral Ligand
    Chen, Y. M.
    Xiong, X. J.
    Huang, L. C.
    Chen, Y. H.
    Huang, Z.
    Zhang, W. J.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 61 (06) : 873 - 879
  • [37] Synthesis, crystal structure and properties of a one-dimensional polymeric copper(II) complex of tetrachlorophthalate
    Yang, SY
    Long, LS
    Wu, ZY
    Zhan, MX
    Huang, RB
    Zheng, LS
    TRANSITION METAL CHEMISTRY, 2002, 27 (05) : 546 - 549
  • [38] Synthesis, crystal structure and properties of a one-dimensional polymeric copper(II) complex of tetrachlorophthalate
    Shi-Yao Yang
    La-Sheng Long
    Zhen-Yi Wu
    Meng-Xiong Zhan
    Rong-Bin Huang
    Lan-Sun Zheng
    Transition Metal Chemistry, 2002, 27 : 546 - 549
  • [39] Synthesis and structure of one-dimensional linear copper(II) coordination polymer bridged by dicyclopentanopyrazine
    Nakano, Keiji
    Miyata, Kengo
    Kitamura, Masato
    HETEROCYCLES, 2007, 74 : 239 - 243
  • [40] Synthesis, crystal structure and antibacterial activity of one-dimensional chain calcium(II) complex
    Tai, Xi-Shi
    ADVANCED RESEARCH ON INDUSTRY, INFORMATION SYSTEMS AND MATERIAL ENGINEERING, PTS 1-7, 2011, 204-210 : 144 - 147
12345