Synthesis and Isomerization of N-Fused Tetraphenylporphyrin Ruthenium(II) Complexes

被引：12

作者：

Toganoh, Motoki ^{[1
]}

Matsuo, Hideaki ^{[1
]}

Sato, Ayumi ^{[1
]}

Hirashima, Yuya ^{[1
]}

Furuta, Hiroyuki ^{[1
,2
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Nishi Ku, Fukuoka 8190395, Japan

[2] Kyushu Univ, Ctr Mol Syst, Nishi Ku, Fukuoka 8190395, Japan

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 16期

关键词：

PORPHYRIN; REACTIVITY; DERIVATIVES; REARRANGEMENTS; SUBSTITUTION;

D O I：

10.1021/ic401314a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three possible isomers of N-fused tetraphenylporphyrin ruthenium complexes, Ru(NFTPp)Cl(CO)(2) (2a-c), were isolated and fully characterized by NMR, IR, CV, UV-vis-NIR absorption, and X-ray crystallographic analyses. Each isomer was stable at ambient conditions and isomerization among 2a-c occurred at elevated temperature both in solution and in a solid state, through the intramolecular rotational pathways. Electronic structures of 2a-c were analyzed in detail by DFT study to reveal appreciable differences in the interaction between the NFTPp ligand and the Ru-Cl moiety.

引用

页码：9613 / 9619

页数：7

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