Synthesis and Characterization of N-Fused Porphyrin Rhodium Complex with an Isomerized Cyclooctadiene Ligand

被引：4
|
作者：
Abraham, Jibin Alex [1 ,2 ]
Mori, Shigeki [3 ]
Ishida, Masatoshi [1 ,2 ]
Furuta, Hiroyuki [1 ,2 ]
机构：
[1] Kyushu Univ, Dept Appl Chem, Grad Sch Engn, Nishi Ku, 744 Moto Oka, Fukuoka 8190395, Japan
[2] Kyushu Univ, Ctr Mol Syst, Nishi Ku, 744 Moto Oka, Fukuoka 8190395, Japan
[3] Ehime Univ, Adv Res Support Ctr, Matsuyama, Ehime 7908577, Japan
来源：
CHEMISTRY LETTERS | 2021年 / 50卷 / 09期
关键词：
N-fused porphyrin; Rhodium complexation; Cyclooctadiene isomerization; CHEMISTRY;
D O I：
10.1246/cl.210381
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel sandwich N-fused porphyrin rhodium complex (Rh-1-Br) comprising a brominated N-fused porphyrin (1-Br) and an isomerized cyclooctadiene ligand was synthesized and characterized. X-ray crystallographic analysis revealed a 1,5-cyclooctadiene isomerization into allylic C-H activated k(1), eta(3)-C8H12 unit bound to the Rh center. The rotational dynamics of k(1), eta(3)-C8H12 ring in Rh-1-Br was discussed using (HNMR)-H-1 spectroscopic analysis and DFT calculation.
引用
收藏
页码：1707 / 1709
页数：3
相关论文
共 50 条
  • [1] Iridium Complex of N-Fused Bilatrienone: Oxidative Cleavage of N-Fused Porphyrin Induced by Iridium-Cyclooctadiene Complexation
    Abraham, Jibin Alex
    Mori, Shigeki
    Ishida, Masatoshi
    Furuta, Hiroyuki
    CHEMISTRY-A EUROPEAN JOURNAL, 2021, 27 (32) : 8268 - 8272
  • [2] Doubly N-Fused Porphyrin
    Toganoh, Motoki
    Kimura, Tomoyuki
    Uno, Hidemitsu
    Furuta, Hiroyuki
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (46) : 8913 - 8916
  • [3] Marriage of an N-Fused and a Regular Porphyrin in a Cofacial Ligand System
    Schissler, Christoph
    Schneider, Erik K.
    Rotter, Michael
    Notter, Silke
    Geier, Carsten
    Weis, Patrick
    Kappes, Manfred M.
    Braese, Stefan
    ORGANOMETALLICS, 2023, 42 (15) : 1882 - 1889
  • [4] Synthesis and properties of rhenium tricarbonyl complex bearing N-fused tetraphenylporphyrin ligand
    Toganoh, M
    Ishizuka, T
    Furuta, H
    CHEMICAL COMMUNICATIONS, 2004, (21) : 2464 - 2465
  • [5] N-Fused Porphyrin: A Maverick Member of the Porphyrin Family
    Toganoh, Motoki
    Furuta, Hiroyuki
    CHEMISTRY LETTERS, 2019, 48 (07) : 615 - 622
  • [6] `N-fused porphyrin' from N-confused porphyrin
    Furuta, Hiroyuki
    Ishizuka, Tomoya
    Osuka, Atsuhiro
    Ogawa, Takuji
    Journal of the American Chemical Society, 1999, 121 (12):
  • [7] N-fused porphyrin from N-confused porphyrin
    Furuta, H
    Ishizuka, T
    Osuka, A
    Ogawa, T
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (12) : 2945 - 2946
  • [8] Stereoretentive Ligand Exchange Reactions of N-Fused Porphyrin Ruthenium(II) Complexes
    Matsuo, Hideaki
    Toganoh, Motoki
    Ishida, Masatoshi
    Mori, Shigeki
    Furuta, Hiroyuki
    INORGANIC CHEMISTRY, 2017, 56 (22) : 13842 - 13851
  • [9] Synthesis of N-fused "Lactendiynes"
    Banfi, L
    Guanti, G
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 1998, 1998 (08) : 1543 - 1548
  • [10] Synthesis, Reactivity, and Properties of N-Fused Porphyrin Manganese(I) Tricarbonyl Complexes
    Ikeda, Shinya
    Toganoh, Motoki
    Furuta, Hiroyuki
    INORGANIC CHEMISTRY, 2011, 50 (13) : 6029 - 6043
12345