Tetrakis(bis(trimethylsilyl)amido)uranium(IV): Synthesis and Reactivity

被引：45
|
作者：
Lewis, Andrew J. [1 ]
Williams, Ursula J. [1 ]
Carroll, Patrick J. [1 ]
Schelter, Eric J. [1 ]
机构：
[1] Univ Penn, Dept Chem, P Roy & Diana T Vagelos Labs, Philadelphia, PA 19104 USA
来源：
INORGANIC CHEMISTRY | 2013年 / 52卷 / 13期
基金：
美国国家科学基金会;
关键词：
ELECTRONIC-STRUCTURE; URANIUM; COMPLEXES; CHEMISTRY; ARYLOXIDE; DERIVATIVES; REDUCTION; OXIDATION; POCKET; AMIDE;
D O I：
10.1021/ic401181j
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of the sterically saturated uranium(IV) complex U[N(SiMe3)(2)](4) (1) is demonstrated from the one electron oxidation of U[N(SiMe3)(2)](3) with a variety of oxidants in THF. A high yielding synthesis of 1 directly from UI3(THF)(4) is provided
引用
收藏
页码：7326 / 7328
页数：3
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