Tetrakis(bis(trimethylsilyl)amido)uranium(IV): Synthesis and Reactivity

被引：45

作者：

Lewis, Andrew J. ^{[1
]}

Williams, Ursula J. ^{[1
]}

Carroll, Patrick J. ^{[1
]}

Schelter, Eric J. ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, P Roy & Diana T Vagelos Labs, Philadelphia, PA 19104 USA

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 13期

基金：

美国国家科学基金会;

关键词：

ELECTRONIC-STRUCTURE; URANIUM; COMPLEXES; CHEMISTRY; ARYLOXIDE; DERIVATIVES; REDUCTION; OXIDATION; POCKET; AMIDE;

D O I：

10.1021/ic401181j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of the sterically saturated uranium(IV) complex U[N(SiMe3)(2)](4) (1) is demonstrated from the one electron oxidation of U[N(SiMe3)(2)](3) with a variety of oxidants in THF. A high yielding synthesis of 1 directly from UI3(THF)(4) is provided

引用

页码：7326 / 7328

页数：3

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