New polymeric catalysts used in the oxidation of organic compounds

被引：0
|
作者：
Pielichows, J [1 ]
Kowalski, G [1 ]
Goldyn, G [1 ]
机构：
[1] Politech Krakowska, Samodzienina Katedra Chem & Technol Tworzyw Sztuc, PL-31155 Krakow, Poland
来源：
PRZEMYSL CHEMICZNY | 2003年 / 82卷 / 8-9期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Polyaniline, poly-o-toluidine, or poly-o-anisidine supported cobalt(11) and nickel(II) (acetate, chloride, nitrate or sulfate; or Schiff's base) complexes were prepared and used as heterogeneous catalysts to epoxidize trans-stilbene, 1-dodecene, 1-decene, 1-octene, and cyclooctene, with O-2 in acetonitrile as solvent at 20 and 60degreesC and with isobutyraldehyde as "oxygen transfer"agent. The catalysts can efficiently (up to 99%) epoxidize unsaturated compounds and oxidize alcohols and aromatic hydrocarbons.
引用
收藏
页码：940 / 941
页数：2
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