New polymeric catalysts used in the oxidation of organic compounds

被引：0

作者：

Pielichows, J ^{[1
]}

Kowalski, G ^{[1
]}

Goldyn, G ^{[1
]}

机构：

[1] Politech Krakowska, Samodzienina Katedra Chem & Technol Tworzyw Sztuc, PL-31155 Krakow, Poland

来源：

PRZEMYSL CHEMICZNY | 2003年 / 82卷 / 8-9期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polyaniline, poly-o-toluidine, or poly-o-anisidine supported cobalt(11) and nickel(II) (acetate, chloride, nitrate or sulfate; or Schiff's base) complexes were prepared and used as heterogeneous catalysts to epoxidize trans-stilbene, 1-dodecene, 1-decene, 1-octene, and cyclooctene, with O-2 in acetonitrile as solvent at 20 and 60degreesC and with isobutyraldehyde as "oxygen transfer"agent. The catalysts can efficiently (up to 99%) epoxidize unsaturated compounds and oxidize alcohols and aromatic hydrocarbons.

引用

页码：940 / 941

页数：2

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