Synthesis, crystal structure and optical properties of Ba5V3O12F

被引：16

作者：

Kang, Jing ^{[1
,2
,3
,4
]}

Yang, Yun ^{[1
,2
,3
]}

Pan, Shilie ^{[1
,2
,3
]}

Yu, Hongwei ^{[1
,2
,3
,4
]}

Zhou, Zhongxiang ^{[1
,2
,3
]}

机构：

[1] Key Lab Funct Mat & Devices Special Environm CAS, Xian, Peoples R China

[2] Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi, Peoples R China

[3] Xinjiang Tech Inst Phys & Chem CAS, Urumqi 830011, Peoples R China

[4] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2014年 / 1056卷

基金：

中国国家自然科学基金;

关键词：

Ba5V3O12F; Apatite; Vanadium-oxide-based compounds; Synthesis; Crystal structure; LOCKED ND-LUVO4 LASER; POLAR OXIDES; LUMINESCENT PROPERTIES; APATITE-STRUCTURE; VANADIUM; GROWTH;

D O I：

10.1016/j.molstruc.2013.10.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Colorless and transparent Ba(5)V(3)O(12)Fcrystal has been synthesized by solid state reaction and characterized by single-crystal X-ray diffraction and physical properties analyses. Ba5V3O12F crystallizes in the hexagonal system with space group P6(3)/m. The structure of apatite-like compound Ba5V3O12F can be described on the basis of a "framework" made of Ba(2)O-6 polyhedra and VO4 tetrahedra, which form [0 0 1]-channels filled with Ba(1) cations and F anions. The VO4 groups presented in the sample are identified by Fourier transform infrared spectrum. UV-Vis-NIR diffuse reflectance spectrum of Ba5V3O12F shows that it has a wide transmittance range from 322 to 2600 nm. Crown Copyright (C) 2013 Published by Elsevier B.V. All rights reserved.

引用

页码：79 / 83

页数：5

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