A new one pot and solvent-free synthesis of nickel porphyrin complex

被引:26
|
作者
Sharma, Rakesh Kumar [1 ]
Ahuja, Gauri [1 ]
Sidhwani, Indu Tucker [1 ]
机构
[1] Univ Delhi, Dept Chem, Green Chem Network Ctr, Delhi 110007, India
关键词
solvent free; one pot synthesis; nickel porphyrin;
D O I
10.1080/17518250903117463
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new one pot and solvent-free synthesis of nickel porphyrin complexis described. This is prepared by condensing pyrrole, benzaldehyde, nickel (II) chloride, and 1,8-diazabicyclo [5.4.0] undec-7-ene as a base. This new method allows higher yields, reduced reaction times, ease of handling, and follows principles of green chemistry. The same complexis also prepared by an alternative route, i.e. first, the porphyrin is prepared and then the insertion of metal ion.
引用
收藏
页码:101 / 105
页数:5
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