A new one pot and solvent-free synthesis of nickel porphyrin complex

被引：26

作者：

Sharma, Rakesh Kumar ^{[1
]}

Ahuja, Gauri ^{[1
]}

Sidhwani, Indu Tucker ^{[1
]}

机构：

[1] Univ Delhi, Dept Chem, Green Chem Network Ctr, Delhi 110007, India

来源：

GREEN CHEMISTRY LETTERS AND REVIEWS | 2009年 / 2卷 / 02期

关键词：

solvent free; one pot synthesis; nickel porphyrin;

D O I：

10.1080/17518250903117463

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new one pot and solvent-free synthesis of nickel porphyrin complexis described. This is prepared by condensing pyrrole, benzaldehyde, nickel (II) chloride, and 1,8-diazabicyclo [5.4.0] undec-7-ene as a base. This new method allows higher yields, reduced reaction times, ease of handling, and follows principles of green chemistry. The same complexis also prepared by an alternative route, i.e. first, the porphyrin is prepared and then the insertion of metal ion.

引用

页码：101 / 105

页数：5

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