Synthesis and Characterization of a Novel Bis-Sulfoxide and Its Evaluation as a Ligand in p-Block Chemistry

被引：4

作者：

Deak, Noemi ^{[1
]}

Thillaye du Boullay, Olivier ^{[1
]}

Mallet-Ladeira, Sonia ^{[3
]}

Moraru, Ionut-Tudor ^{[2
]}

Madec, David ^{[1
]}

Nemes, Gabriela ^{[2
]}

机构：

[1] Univ Toulouse, CNRS, Lab Heterochim Fondamentale & Appl, UMR 5069, 118 Route Narbonne, F-31062 Toulouse, France

[2] Univ Babes Bolyai, Fac Chim Si Ingn Chim, Str Arany Janos Nr 11, Cluj Napoca 400028, Romania

[3] Univ Paul Sabatier, Inst Chim Toulouse, FR2599, 118 Route Narbonne, F-31062 Toulouse, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2020年 / 2020卷 / 39期

关键词：

Bis-sulfoxide; Stannylene; Silicon; p-block element; Phosphorus; PALLADIUM-CATALYZED ARYLATION; THERMAL RACEMIZATION; X-RAY; O; C; O-CHELATED METALLYLENES; ENANTIOSELECTIVE SYNTHESIS; PHOSPHAALKENYL GERMYLENES; PINCER COMPLEXES; ARYL SULFOXIDES; OXIDATION; SULFIDES;

D O I：

10.1002/ejic.202000728

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new aryl bis-sulfoxide derivative was designed, synthetized and structurally characterized in solution and in solid state. The chemical behaviour of the newly obtained 1,3-(para-tolylsulfinyl)-5-tert-butyl-benzene2was evaluated towards tin, silicon and phosphorus containing derivatives. In the case of Sn(II) derivative, the potential of bis-sulfoxide2as a pincer type ligand was suggested.

引用

页码：3729 / 3737

页数：9

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