A possible mechanism for hexagonal void movement observed during sublimation growth of SiC single crystals

被引:3
|
作者
Fujimoto, Tatsuo [1 ]
Tsuge, Hiroshi [1 ]
Katsuno, Masakazu [1 ]
Sato, Shinya [1 ]
Yashiro, Hirokatsu [1 ]
Hirano, Hosei [1 ]
Yano, Takayuki [1 ]
机构
[1] Nippon Steel Corp Ltd, Adv Technol Res Labs, Futtsu, Chiba 2938511, Japan
来源
SILICON CARBIDE AND RELATED MATERIALS 2012 | 2013年 / 740-742卷
关键词
Hexagonal void; micropipe defect; Si-C binary phase diagram; growth instability;
D O I
10.4028/www.scientific.net/MSF.740-742.577
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
A possible mechanism of hexagonal void movement during Physical vapor transport (PVT)-growth is proposed in terms of quasi-equilibrium phase transition process based upon the Si-C binary phase diagram. The hexagonal void movement can be realized when two different reactions occurs simultaneously: (1) SiC(s) solidification and (2) decomposition without graphitization. Further, the kinetic instability of the void movement observed is also discussed, and found to be explainable if the effect of the temperature gradient existing in the crystal grown in conventional PVT-process is included.
引用
收藏
页码:577 / 580
页数:4
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